Transformation of humic acid and halogenated byproduct formation in UV-chlorine processes

doi:10.1016/j.watres.2016.06.051

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 中国科学院饮用水科学与技术重点实验室

	Transformation of humic acid and halogenated byproduct formation in UV-chlorine processes
	An, Xiaoqiang; Qu, Jiuhui; Hu, Chun; Liu, Huijuan; Jiang, Yan; Li, Tong
刊名	WATER RESEARCH
	2016-10-01
卷号	102 期号:0 页码:421-427
关键词	Uv-chlorine Hydroxyl Radical Chlorine Radical Humic Acid Disinfection Byproducts
DOI	10.1016/j.watres.2016.06.051
英文摘要	The synergistic effect of ultraviolet light (UV) and chlorine on the structural transformation of Humic Acid (HA) and formation of chloro-disinfection byproducts (DBPs) in water were investigated, with chlorination as a reference. The transformation and mineralization of HA were enhanced upon co-exposure to UV and chlorine. Electron spin resonance (ESR) studies revealed that hydroxyl radical (center dot OH) and chlorine radical (center dot Cl) were predominant active species in a pH range from 4 to 7, while center dot Cl dominated at pH 2 and pH higher than 7. The impact of different radicals on the transformation of HA was investigated by UV254, fluorescence and TOC measurements. center dot OH were found to be responsible for the removal of chromophoric groups and mineralization of HA, while center dot Cl mainly reacted with HA and intermediates from HA degradation. Due to the competitive and synergistic reaction of center dot OH and center dot Cl with HA, higher removal of HA and lower formation of chloro-DBPs appeared in UV-chlorine than chlorination, thus the combined UV-chlorine processes should be a promising method for water purification. (C) 2016 Published by Elsevier Ltd.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/36220]
专题	生态环境研究中心_中国科学院饮用水科学与技术重点实验室
推荐引用方式 GB/T 7714	An, Xiaoqiang,Qu, Jiuhui,Hu, Chun,et al. Transformation of humic acid and halogenated byproduct formation in UV-chlorine processes[J]. WATER RESEARCH,2016,102(0):421-427.
APA	An, Xiaoqiang,Qu, Jiuhui,Hu, Chun,Liu, Huijuan,Jiang, Yan,&Li, Tong.(2016).Transformation of humic acid and halogenated byproduct formation in UV-chlorine processes.WATER RESEARCH,102(0),421-427.
MLA	An, Xiaoqiang,et al."Transformation of humic acid and halogenated byproduct formation in UV-chlorine processes".WATER RESEARCH 102.0(2016):421-427.