Practical preparation of 2-azido-2-deoxy-beta-D-mannopyranosyl carbonates and their application in the synthesis of oligosaccharides

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 中国科学院环境生物技术重点实验室

	Practical preparation of 2-azido-2-deoxy-beta-D-mannopyranosyl carbonates and their application in the synthesis of oligosaccharides
	Zhang, Hanjun; Yan, Shiqiang; Liang, Xiaomei; Wu, Jingping; Wang, Daoquan; Kong, Fanzuo
刊名	CARBOHYDRATE RESEARCH
	2007-12-28
卷号	342 期号:18 页码:2810-2817
关键词	2-azido-2-deoxy-beta-d-mannopyranose Triflation Azide Displacement
英文摘要	1-O-Allyloxycarbonyl (or ethyloxycarbonyl)-2-azido-2-deoxy-3-O-benzyl (or allyl, or benzoyl)-4,6-O-isopropylidene-beta-D-mannopyranose derivatives were prepared from the corresponding 2-hydroxy-beta-D-glucopyranosyl carbonates in high yields via triflation of the 2-hydroxyl group and subsequent S(N)2 displacement with azide ion. An N-acetyl-mannosamine-containing trisaccharide, a fragment of the putative O10 antigen from Acinetobacter baumannii, was efficiently synthesized using these derivatives. (C) 2007 Published by Elsevier Ltd.
WOS记录号	WOS:000251872000014
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/22670]
专题	生态环境研究中心_中国科学院环境生物技术重点实验室
推荐引用方式 GB/T 7714	Zhang, Hanjun,Yan, Shiqiang,Liang, Xiaomei,et al. Practical preparation of 2-azido-2-deoxy-beta-D-mannopyranosyl carbonates and their application in the synthesis of oligosaccharides[J]. CARBOHYDRATE RESEARCH,2007,342(18):2810-2817.
APA	Zhang, Hanjun,Yan, Shiqiang,Liang, Xiaomei,Wu, Jingping,Wang, Daoquan,&Kong, Fanzuo.(2007).Practical preparation of 2-azido-2-deoxy-beta-D-mannopyranosyl carbonates and their application in the synthesis of oligosaccharides.CARBOHYDRATE RESEARCH,342(18),2810-2817.
MLA	Zhang, Hanjun,et al."Practical preparation of 2-azido-2-deoxy-beta-D-mannopyranosyl carbonates and their application in the synthesis of oligosaccharides".CARBOHYDRATE RESEARCH 342.18(2007):2810-2817.