Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境化学与生态毒理学国家重点实验室

	Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters
	Zhou, Xiao-xia; Lai, Yu-jian; Liu, Rui; Li, Sha-sha; Xu, Jing-wen; Liu, Jing-fu
刊名	ENVIRONMENTAL SCIENCE & TECHNOLOGY
	2017-02-01
卷号	51 期号:23 页码:13816-13824
英文摘要	Efficient separation and preconcentration of trace nanoparticulate silver (NAg) from large-volume environmental waters is a prerequisite for reliable analysis and therefore understanding the environmental processes of silver nanoparticles (AgNPs). Herein, we report the novel use of polyvinylidene fluoride (PVDF) filter membrane for disk-based solid phase extraction (SPE) of NAg in 1 L of water samples with the disk-based SPE system, which consists of a syringe pump and a syringe filter holder to embed the filter membrane. While the PVDF membrane can selectively adsorb NAg in the presence of Ag+, aqueous solution of 2% (m/v) FL-70 is found to efficiently elute NAg. Analysis of NAg is performed following optimization of filter membrane and elution conditions with an enrichment factor of 1000. Additionally, transmission electron microscopy (TEM), UVvis spectroscopy, and size-exclusion chromatography coupled with ICP-MS (SEC-ICP-MS) analysis showed that the extraction gives rise to no change in NAg size or shape, making this method attractive for practical applications. Furthermore, feasibility of the protocol is verified by applying it to extract NAg in four real waters with recoveries of 62.280.2% at 0.0560.58 mu g/L spiked levels. This work will facilitate robust studies of trace NAg transformation and their hazard assessments in the environment.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/39386]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Zhou, Xiao-xia,Lai, Yu-jian,Liu, Rui,et al. Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2017,51(23):13816-13824.
APA	Zhou, Xiao-xia,Lai, Yu-jian,Liu, Rui,Li, Sha-sha,Xu, Jing-wen,&Liu, Jing-fu.(2017).Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters.ENVIRONMENTAL SCIENCE & TECHNOLOGY,51(23),13816-13824.
MLA	Zhou, Xiao-xia,et al."Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters".ENVIRONMENTAL SCIENCE & TECHNOLOGY 51.23(2017):13816-13824.