Facile synthesis of nanostructured Li4Ti5O12/PEDOT:PSS composite as anode material for lithium-ion batteries
Liu, Yan1,2; Tang, Daoping1; Zhong, Haoxiang1; Zhang, Qianyu1; Yang, Jianwen3; Zhang, Lingzhi1
刊名RSC ADVANCES
2016
卷号6期号:98页码:95512-95517
DOI10.1039/c6ra20958k
文献子类Article
英文摘要A poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) coated Li4Ti5O12 (LTO/PP) composite is synthesized by a facile and convenient approach, which involves dispersing LTO in an aqueous solution of PEDOT: PSS, followed by rotary evaporation accompanied by an ultrasonic procedure. After the coating process, LTO is covered by a homogeneous PEDOT: PSS layer, which effectively improves the electrical conductivity and processing capability of LTO to form a more homogeneous electrode sheet, and thus impart more favorable electrochemical kinetics as compared with the pristine LTO electrode. The LTO/PP electrode exhibits better reversible capacity and rate capability compared with the LTO electrode, delivering a reversible capacity of 177.2 mA h g(-1) at 0.1C and reaching a capacity of 169.1 mA h g(-1) with a capacity retention of 97.8% after 100 cycles at 0.5C. At the rate of 10C, the LTO/PP electrode delivers a capacity as high as 161.1 mA h g(-1) (91.0% of the value achieved at 0.1C), as compared to 144.5 mA h g(-1) for the pristine LTO electrode.
WOS关键词CARBON-COATED LI4TI5O12 ; DOPED LI4TI5O12 ; ELECTROCHEMICAL PERFORMANCE ; RATE CAPABILITY ; SECONDARY BATTERIES ; CYCLING PERFORMANCE ; ELECTRODE MATERIAL ; ENERGY-STORAGE ; MICROSPHERES ; NANOFIBERS
语种英语
WOS记录号WOS:000385633100018
资助机构National Natural Science Foundation of China(21573239) ; Guangdong Provincial Project for Science Technology(2014TX01N014/2014A050503050/2015B010135008) ; Natural Science Foundation of Guangdong Province(2016A030310127) ; Guangzhou Municipal Project for Science Technology(2014Y-200219/201509010018)
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/13969]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, 2 NengyuanRd, Guangzhou 510640, Peoples R China
2.Univ Chinese Acad Sci, 19 A Yu Quan Rd, Beijing 100049, Peoples R China
3.Guilin Univ Technol, Coll Chem & Bioengn, 12 Jiangan Rd, Guilin 541004, Guangxi, Peoples R China
推荐引用方式
GB/T 7714
Liu, Yan,Tang, Daoping,Zhong, Haoxiang,et al. Facile synthesis of nanostructured Li4Ti5O12/PEDOT:PSS composite as anode material for lithium-ion batteries[J]. RSC ADVANCES,2016,6(98):95512-95517.
APA Liu, Yan,Tang, Daoping,Zhong, Haoxiang,Zhang, Qianyu,Yang, Jianwen,&Zhang, Lingzhi.(2016).Facile synthesis of nanostructured Li4Ti5O12/PEDOT:PSS composite as anode material for lithium-ion batteries.RSC ADVANCES,6(98),95512-95517.
MLA Liu, Yan,et al."Facile synthesis of nanostructured Li4Ti5O12/PEDOT:PSS composite as anode material for lithium-ion batteries".RSC ADVANCES 6.98(2016):95512-95517.
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