Production of jet fuel range biofuels by catalytic transformation of triglycerides based oils
Wu, Xiaoping1; Jiang, Peiwen1; Jin, Feng1; Liu, Junxu1; Zhang, Yiheng1; Zhu, Lijuan1; Xia, Tongyan1; Shao, Kuanliang1; Wang, Tiejun2; Li, Quanxin1
刊名FUEL
2017-01-15
卷号188页码:205-211
关键词Triglycerides Based Oils Cracking Alkylation Jet Fuel Components
DOI10.1016/j.fuel.2016.10.030
文献子类Article
英文摘要This work demonstrated that triglycerides based vegetable oils were directly converted into cycloparaffinic and aromatic components in jet fuel by a three-step process. This process involved the catalytic cracking of vegetable oils into light aromatics over the zeolite catalyst (HZSM-5(80)), followed by the aromatic alkylation of light aromatics using the ionic liquid of [bmim] Cl-2AlCl(3) and the hydrogenation of aromatics over the Pd/AC catalyst. The production of C-8-C-15 aromatics with an 86.2 wt% in the aromatic biofuel was achieved by the room temperature alkylation at 25 degrees C for 30 min. The carbon number distribution in the resulting biofuels was readily adjustable to the desired range by varying the reaction time. The aromatic and cycloparaffinic biofuels obtained basically meet the requirements of jet fuels based on the combustion heat, the H/C mol ratio and the average molecular formulation. (C) 2016 Elsevier Ltd. All rights reserved.
WOS关键词BIO-OIL ; HYDROCARBON FUELS ; FATTY-ACIDS ; PALM OIL ; CONVERSION ; BIOMASS ; DIESEL ; CHEMICALS ; CRACKING ; CYCLOPENTANONE
语种英语
WOS记录号WOS:000386770400023
资助机构National Key Basic Program of China (973 Program)(2013CB228105) ; Program for Changjiang Scholars and Innovative Research Team in University ; Fundamental Research Funds for the Central Universities(wk 2060190040)
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/13943]  
专题中国科学院广州能源研究所
作者单位1.Univ Sci & Technol China, Dept Chem Phys, Key Lab Urban Pollutant Convers, Chinese Acad Sci,Anhui Key Lab Biomass Clean Ener, Hefei 230026, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Wu, Xiaoping,Jiang, Peiwen,Jin, Feng,et al. Production of jet fuel range biofuels by catalytic transformation of triglycerides based oils[J]. FUEL,2017,188:205-211.
APA Wu, Xiaoping.,Jiang, Peiwen.,Jin, Feng.,Liu, Junxu.,Zhang, Yiheng.,...&Li, Quanxin.(2017).Production of jet fuel range biofuels by catalytic transformation of triglycerides based oils.FUEL,188,205-211.
MLA Wu, Xiaoping,et al."Production of jet fuel range biofuels by catalytic transformation of triglycerides based oils".FUEL 188(2017):205-211.
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