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The lubrication effectiveness of dialkylpentasulfide in synthetic ester and its emulsion
Zheng, Ganlin1; Ding, Tongmei1; Zheng, Lei2; Ren, Tianhui1
刊名Tribology international
2018-06-01
卷号122页码:76-83
关键词Synthetic ester Emulsion Alkyl sulfides Tribochemical process
ISSN号0301-679X
DOI10.1016/j.triboint.2018.02.041
通讯作者Ren, tianhui(thren@sjtu.edu.cn)
英文摘要The application of dialkylpentasulfide (dps) in synthetic ester (pentaerythritol tetraoleate known as peto ester) and its emulsion is studied in this paper. peto ester blended with dps shows good antiwear, friction reducing and extreme pressure performance, while peto emulsion doped with dps exhibits only excellent extreme pressure properties. the above difference originates from the tribofilm formed on the worn surface by tribochemical reaction. sem-eds and xanes are applied to determine the relationship between tribochemical products and lubrication effectiveness. the tribofilm is composed of feso4, fes, fes2 and feso3. dps in peto ester and peto emulsion undergoes tribochemical reaction dominated by sulfidation and thermal oxidation respectively, resulting in distinct tribological properties. this provides an essential explanation for the improvement of tribological properties of dps in peto ester and emulsion, and also indicates that sulfur is not fitted as antiwear, friction-reducing additive in water based system.
WOS关键词IONIC LIQUID ; RAPESEED OIL ; INTERFACIAL MECHANISM ; XANES SPECTROSCOPY ; TRIBOCHEMICAL WEAR ; HUMID ENVIRONMENT ; ZDDP TRIBOFILM ; ANTIWEAR FILMS ; MINERAL-OIL ; ADDITIVES
WOS研究方向Engineering
WOS类目Engineering, Mechanical
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000430522500009
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2178161
专题高能物理研究所
通讯作者Ren, Tianhui
作者单位1.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Thin Film & Microfabricat, Shanghai 200240, Peoples R China
2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Ganlin,Ding, Tongmei,Zheng, Lei,et al. The lubrication effectiveness of dialkylpentasulfide in synthetic ester and its emulsion[J]. Tribology international,2018,122:76-83.
APA Zheng, Ganlin,Ding, Tongmei,Zheng, Lei,&Ren, Tianhui.(2018).The lubrication effectiveness of dialkylpentasulfide in synthetic ester and its emulsion.Tribology international,122,76-83.
MLA Zheng, Ganlin,et al."The lubrication effectiveness of dialkylpentasulfide in synthetic ester and its emulsion".Tribology international 122(2018):76-83.
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