| Surface step decoration of isolated atom as electron pumping: atomic-level insights into visible-light hydrogen evolution | |
| Wu, Xin1; Zhang, Huabin2; Dong, Juncai3; Qiu, Mei4; Kong, Jintao1; Zhang, Yongfan4; Li, Yang1; Xu, Guilan1; Zhang, Jian1; Ye, Jinhua2 | |
| 刊名 | Nano energy
 |
| 2018-03-01 | |
| 卷号 | 45页码:109-117 |
| 关键词 | Isolated atom Surface step Hydrogen evolution Electron pumping Catalysis |
| ISSN号 | 2211-2855 |
| DOI | 10.1016/j.nanoen.2017.12.039 |
| 通讯作者 | Zhang, huabin(zhang.huabin@ntu.edu.sg) ; Zhang, jian(zhj@fjirsm.ac.cn) ; Ye, jinhua(jinhua.ye@nims.go.jp) |
| 英文摘要 | Here we realize the decoration of isolated platinum atoms onto the surface step of cds nanowires. the single-atom co-catalyst with high stability can realize maximum atom efficiency and significantly boost electron-hole separation efficiency in chromophore units, generating a greatly enhanced photocatalytic hydrogen evolution performance, 7.69 times as high as pt nanoparticles do and 63.77 times higher than that of bare cds nanowires. directional migrations of photogenerated excitons from the conduction band of cds to catalytic platinum centers have been witnessed by transient absorption spectroscopy, leading to the supply of long-lived electrons for highly efficient photocatalytic hydrogen evolution. density functional theory calculations further confirm that the excellent catalytic performance is associated with positively charged platinum sites with partially vacant 5d orbitals, which change distribution of charge density and facilitate higher excited carrier density. |
| WOS关键词 | INITIO MOLECULAR-DYNAMICS ; PHOTOCATALYTIC H-2 EVOLUTION ; AUGMENTED-WAVE METHOD ; SINGLE-ATOM ; PREFERENTIAL OXIDATION ; CERIA CATALYSTS ; CDS NANOWIRES ; SEMICONDUCTOR ; GRAPHENE ; METALS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000425396400014 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2178040 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Zhang, Huabin; Zhang, Jian; Ye, Jinhua |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 4.Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Xin,Zhang, Huabin,Dong, Juncai,et al. Surface step decoration of isolated atom as electron pumping: atomic-level insights into visible-light hydrogen evolution[J]. Nano energy,2018,45:109-117. |
| APA | Wu, Xin.,Zhang, Huabin.,Dong, Juncai.,Qiu, Mei.,Kong, Jintao.,...&Ye, Jinhua.(2018).Surface step decoration of isolated atom as electron pumping: atomic-level insights into visible-light hydrogen evolution.Nano energy,45,109-117. |
| MLA | Wu, Xin,et al."Surface step decoration of isolated atom as electron pumping: atomic-level insights into visible-light hydrogen evolution".Nano energy 45(2018):109-117. |
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