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	Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates
	Liu, Shuyang1; Jie, Jiyang1; Yu, Jipan2,3; Yang, Xiaobo1
刊名	Advanced synthesis & catalysis
	2018-01-17
卷号	360期号:2页码:267-271
关键词	Visible light induced Radical Migration Trifluoromethylation Enol triflate
ISSN号	1615-4150
DOI	10.1002/adsc.201701051
通讯作者	Yang, xiaobo(bxy1223@gmail.com)
英文摘要	Herein, we reported a novel method to synthesize alpha-trifluoromethylated ketones from enol triflates. involving a cascade sulfur dioxide extrusion and a cf3 (trifluoromethyl) radical addition process, this reaction proceeds at room temperature and is driven by visible light irradiation. this protocol bears good functional group compatibility, which can generate the desired products in good to excellent yields even in gram scale. it is hoped that this approach to generate cf3 radicals from enol triflates can be used in other radical-involved reactions.
WOS关键词	RADICAL TRIFLUOROMETHYLATION ; ELECTROPHILIC TRIFLUOROMETHYLATION ; PHOTOREDOX CATALYSIS ; ROOM-TEMPERATURE ; OXIDATIVE TRIFLUOROMETHYLATION ; MEDIATED TRIFLUOROMETHYLATION ; CARBONYL-COMPOUNDS ; FUNCTIONAL-GROUPS ; HIGHLY EFFICIENT ; LANGLOIS REAGENT
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Organic
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000422659800009
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2177870
专题	高能物理研究所
通讯作者	Yang, Xiaobo
作者单位	1.Shenyang Normal Univ, Inst Catalysis Energy & Environm, Coll Chem & Chem Engn, Shenyang 110034, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Radiat & Nucl Energy Technol, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Shuyang,Jie, Jiyang,Yu, Jipan,et al. Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates[J]. Advanced synthesis & catalysis,2018,360(2):267-271.
APA	Liu, Shuyang,Jie, Jiyang,Yu, Jipan,&Yang, Xiaobo.(2018).Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates.Advanced synthesis & catalysis,360(2),267-271.
MLA	Liu, Shuyang,et al."Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates".Advanced synthesis & catalysis 360.2(2018):267-271.

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