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	Bimetallic uranyl organic frameworks supported by transition-metal-ion-based metalloligand motifs: synthesis, structure diversity, and luminescence properties
	Zhao, Ran1,2; Mei, Lei1,2; Hu, Kong-qiu1,2; Tian, Ming1,2; Chai, Zhi-fang1,2,3,4; Shi, Wei-qun1,2
刊名	Inorganic chemistry
	2018-05-21
卷号	57期号:10页码:6084-6094
ISSN号	0020-1669
DOI	10.1021/acs.incagchem.8h00634
通讯作者	Shi, wei-qun(shiwq@ihep.ac.cn)
英文摘要	A bifunctional ligand, 2,2'-bipyridine-4,4'-dicarboxylic acid (h(2)bpdc), has been used in the investigation of constructing bimetallic uranyl organic frameworks (uofs). seven novel uranyl transition metal bimetallic coordination polymers, [(uo2)zn(bpdc)(2)](n) (1), [cd(uo2)(bpdc)(2)(h2o)(2.) 2h(2)o](n) (2), [cu(uo2)(bpdc)(so4)(h2o)(3.)2h(2)o](n) (3), [cucl-(uo2) (bpdc) (hbpdc) (h2o)(2.)h2o](n) (4), [cu(uo2)-(bpdc)(2)(h2o)](n) (5), [co-2(uo2)(3)(bpdc)(6)](n) (6), and [co-3(uo2)(4)(bpdc)(8)(hbpdc)(h2o)(2)]n (7), have been successfully constructed through the assembly of various transition-metal salts, uranyl ions, and h(2)bpdc ligands under hydrothermal conditions. uofs 1, 5, 6, and 7 adopt three-dimensional (3d) frameworks with different architectures; uofs 2 and 3 exhibit two-dimensional (2d) wavelike and stairlike layers, respectively, while uof 4 is a one-dimensional (1d) chain assembly. these uofs include a wide range of dimensionalities (id-3d), interpenetrated frameworks, and cation cation interaction species, suggesting that anion-dependent structure regulation based on the metalloligand [m(bpdc)(m)](n)-motifs, the coordination modes of the metal centers and bpdc(2)-ligands, along with the reaction temperature, has a remarkable influence on the formation of bimetallic uofs, which could be a representative system for the structural modulation of uofs with various dimensionalities and structures. furthermore, the thermal stability and luminescent properties of compounds 1, 3, and 6 are also investigated.
WOS关键词	SELECTIVE DYE ADSORPTION ; COORDINATION POLYMERS ; HETEROMETALLIC COMPLEXES ; AQUEOUS-SOLUTIONS ; HYBRID MATERIALS ; ACID ; TOPOLOGY ; 4,4-DICARBOXY-2,2-BIPYRIDINE ; FLUORESCENCE ; DEHYDRATION
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000433013600040
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2177566
专题	高能物理研究所
通讯作者	Shi, Wei-qun
作者单位	1.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China 3.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Ran,Mei, Lei,Hu, Kong-qiu,et al. Bimetallic uranyl organic frameworks supported by transition-metal-ion-based metalloligand motifs: synthesis, structure diversity, and luminescence properties[J]. Inorganic chemistry,2018,57(10):6084-6094.
APA	Zhao, Ran,Mei, Lei,Hu, Kong-qiu,Tian, Ming,Chai, Zhi-fang,&Shi, Wei-qun.(2018).Bimetallic uranyl organic frameworks supported by transition-metal-ion-based metalloligand motifs: synthesis, structure diversity, and luminescence properties.Inorganic chemistry,57(10),6084-6094.
MLA	Zhao, Ran,et al."Bimetallic uranyl organic frameworks supported by transition-metal-ion-based metalloligand motifs: synthesis, structure diversity, and luminescence properties".Inorganic chemistry 57.10(2018):6084-6094.

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