Co-P/graphene alloy catalysts doped with Cu and Ni for efficient photocatalytic hydrogen generation | |
Wu YQ(吴玉琪); Wu YQ(吴玉琪)1; Guo, Yueping1,2; Zhen WL(甄文龙)1; Lv GX(吕功煊); Lu GX(吕功煊)1 | |
刊名 | New Journal of Chemistry |
2017 | |
卷号 | 41期号:22页码:13804-13811 |
ISSN号 | 1144-0546 |
DOI | 10.1039/c7nj01598d |
英文摘要 | Developing low-cost and high-efficiency photocatalysts for hydrogen production from solar water splitting is an intriguing and challenging objective. Co–P-based ternary alloy Co–M–P (M: Cu, Ni) cocatalysts decorated on graphene (GP) were prepared by doping Cu and Ni via an in situ synthesis strategy, and the photocatalytic performances for H2 generation were systematically studied under visible light irradiation. The structure, morphology, chemical composition, and surface electronic state of the catalysts were studied using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) techniques. The results indicated that the Co–Cu–P and Co–Ni–P alloys were active co-catalysts for photocatalytic H2 evolution under visible light irradiation, and the partially oxidized Co species played an important role in enhancing efficient H2 generation evidenced by XPS and XRD characterizations. For the Co–Cu–P/GP (15%) and Co–Ni–P/GP (15%) catalysts, the H2 generation rates reached 44.5 and 36.1 mmol h−1 gCo−1, respectively. The apparent quantum efficiency (AQE) of Co–Cu–P/GP (15%) and Co–Ni–P/GP (10%) samples reached 23.6 and 14.8% at 430 nm, respectively. Multi-cycle experiments indicated that both Co–Cu–P/GP (15%) and Co–Ni–P/GP (10%) catalysts presented a good stability in photocatalytic H2 evolution reactions. The Co–Ni–P and Co–Cu–P alloy materials are promising catalysts for photocatalytic H2 evolution. |
学科主题 | 物理化学与绿色催化 |
资助项目 | 环境催化与氢能研究组 |
语种 | 英语 |
WOS记录号 | WOS:000414440000069 |
资助机构 | the NSFC (Grant No. 21373245;21433007) |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22764] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Wu YQ(吴玉琪); Lv GX(吕功煊) |
作者单位 | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Expt Chem Teaching Ctr, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Wu YQ,Wu YQ,Guo, Yueping,et al. Co-P/graphene alloy catalysts doped with Cu and Ni for efficient photocatalytic hydrogen generation[J]. New Journal of Chemistry,2017,41(22):13804-13811. |
APA | 吴玉琪,Wu YQ,Guo, Yueping,Zhen WL,吕功煊,&Lu GX.(2017).Co-P/graphene alloy catalysts doped with Cu and Ni for efficient photocatalytic hydrogen generation.New Journal of Chemistry,41(22),13804-13811. |
MLA | 吴玉琪,et al."Co-P/graphene alloy catalysts doped with Cu and Ni for efficient photocatalytic hydrogen generation".New Journal of Chemistry 41.22(2017):13804-13811. |
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