Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines

doi:10.1002/adsc.201700583

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 苏州研究院

	Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines
	Kuan, Suzie Hui Chin 1,2; Sun, Wei 1; Wang L(王露)1; Xia CG(夏春谷)1 ; Tay, Meng Guan 2; Liu C(刘超)1; Liu C(刘超)
刊名	Advanced Synthesis & Catalysis
	2017
卷号	359 期号:20 页码:3484-3489
关键词	Double Carbonylation Glyoxal Isatin Synthesis Anilines
ISSN号	1615-4150
DOI	10.1002/adsc.201700583
英文摘要	A novel double carbonylation process has been demonstrated with easily available HCOCOH (glyoxal) as the double carbonylation reagent. Simple CuCl₂·2H₂O (copper(II) chloride dihydrate) was used as the oxidant for this transformation. Under optimized reaction conditions, various primary and secondary anilines were double- carbonylated to afford their corresponding isatins (26 examples, up to 80% yields).
学科主题	物理化学与绿色催化
资助项目	均相催化研究组
语种	英语
WOS记录号	WOS:000413673600005
资助机构	the National Natural Science Foundation of China (21673261;21603245;21633013);the State Key Laboratory for Oxo Synthesis and Selective Oxidation (OSSO), Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences;CAS Interdisciplinary Innovation Team;Young Elite Scientist Sponsorship Program by CAST;MGT and SHCK thank to Malaysian Toray Science Foundation (MTSF) for research financial support under grant number of GL(F07)/MTSF/2014(14)
内容类型	期刊论文
源URL	[http://ir.licp.ac.cn/handle/362003/22529]
专题	兰州化学物理研究所_苏州研究院兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Liu C(刘超)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Malaysia Sarawak, Fac Resource Sci & Technol, Dept Chem, Kota Samarahan 94300, Sarawak, Malaysia
推荐引用方式 GB/T 7714	Kuan, Suzie Hui Chin,Sun, Wei,Wang L,et al. Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines[J]. Advanced Synthesis & Catalysis,2017,359(20):3484-3489.
APA	Kuan, Suzie Hui Chin.,Sun, Wei.,Wang L.,Xia CG.,Tay, Meng Guan.,...&刘超.(2017).Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines.Advanced Synthesis & Catalysis,359(20),3484-3489.
MLA	Kuan, Suzie Hui Chin,et al."Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines".Advanced Synthesis & Catalysis 359.20(2017):3484-3489.