The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction

doi:10.1016/j.tetasy.2017.05.013

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction
	Xu DQ(徐大乾)1,2; Sun QS(孙强盛)2 ; Quan, Zhengjun 1; Sun W(孙伟)2 ; Wang, Xicun 1; Sun W(孙伟)
刊名	Tetrahedron: Asymmetry
	2017
卷号	28 期号:7 页码:954-963
ISSN号	0957-4166
DOI	10.1016/j.tetasy.2017.05.013
英文摘要	A series of chiral tridentate ligands derived from readily available enantiopure L-proline were designed and synthesized. The ligands together with Cu(OAc)₂ were successfully used in asymmetric Henry reactions. Various structurally divergent aldehydes and nitromethane were converted into versatile beta-nitro alcohols in MeOH at room temperature with very good yields (up to 85%) and enantioselectivities (up to 86%).
学科主题	物理化学与绿色催化
资助项目	仿生与生物催化研究组
语种	英语
WOS记录号	WOS:000406571800008
资助机构	the National Natural Science Foundation of China (21473226;21362031)
内容类型	期刊论文
源URL	[http://ir.licp.ac.cn/handle/362003/22441]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_苏州研究院
通讯作者	Wang, Xicun; Sun W(孙伟)
作者单位	1.College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, and Suzhou Research Center of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China
推荐引用方式 GB/T 7714	Xu DQ,Sun QS,Quan, Zhengjun,et al. The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction[J]. Tetrahedron: Asymmetry,2017,28(7):954-963.
APA	Xu DQ,Sun QS,Quan, Zhengjun,Sun W,Wang, Xicun,&孙伟.(2017).The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction.Tetrahedron: Asymmetry,28(7),954-963.
MLA	Xu DQ,et al."The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction".Tetrahedron: Asymmetry 28.7(2017):954-963.