Promotion of the excited electron transfer over Ni- and Co -sulfide co-doped g-C3N4 photocatalyst (g-C3N4/NixCo1-xS2) for hydrogen Production under visible light irradiation | |
Fan, Kai1; Jin ZL(靳治良)1; Yang, Hao1; Liu, Duanduan1; Hu HY(胡红岩)2; Bi YP(毕迎普)2; Jin ZL(靳治良); Hu HY(胡红岩) | |
刊名 | Scientific Reports |
2017 | |
卷号 | 7页码:7710(1-10) |
ISSN号 | 2045-2322 |
DOI | 10.1038/s41598-017-08163-y |
英文摘要 | A Ni- and Co- sulfide co-doped g-C3N4 photocatalyst (g-C3N4/NixCo1−xS2) was prepared by hydrothermal method and this photocatalyst, namely, g-C3N4/NixCo1−xS2 shown excellent photocatalytic properties due to the special structure of Ni-Co-S with boundary different exposure to active site of transition metal-metal (Ni-Co) active planes. With the introduction of Co atoms, the H2 production amount reached the maximum about 400.81 μmol under continuous visible light irradiation for 4 hours based on the efficiently charge separation and greatly improved electron transfer resulted from the presence of sufficient active exposure at the boundary. The serial studies shown that the existence of Ni-Co-S structure over g-C3N4 active surface is the key factor of activity affections by means of several characterizations such as SEM, XRD, XPS diffuse reflectance etc. and the results of which were in good agreement with each other. A possible reaction mechanism over eosin Y-sensitized g-C3N4/NixCo1−xS2 photocatalyst under visible light irradiation was proposed. |
学科主题 | 物理化学与绿色催化 |
资助项目 | 能源与环境纳米催化材料研究组;环境催化与氢能研究组 |
语种 | 英语 |
WOS记录号 | WOS:000407295200009 |
资助机构 | the Chinese National Natural Science Foundation (41663012;21603274);the Post-graduated Innovation Research Program of North Minzu University (YCX 1777) |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22437] |
专题 | 兰州化学物理研究所_ERC国家工程研究中心 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Jin ZL(靳治良); Hu HY(胡红岩) |
作者单位 | 1.North Minzu Univ, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Kai,Jin ZL,Yang, Hao,et al. Promotion of the excited electron transfer over Ni- and Co -sulfide co-doped g-C3N4 photocatalyst (g-C3N4/NixCo1-xS2) for hydrogen Production under visible light irradiation[J]. Scientific Reports,2017,7:7710(1-10). |
APA | Fan, Kai.,Jin ZL.,Yang, Hao.,Liu, Duanduan.,Hu HY.,...&胡红岩.(2017).Promotion of the excited electron transfer over Ni- and Co -sulfide co-doped g-C3N4 photocatalyst (g-C3N4/NixCo1-xS2) for hydrogen Production under visible light irradiation.Scientific Reports,7,7710(1-10). |
MLA | Fan, Kai,et al."Promotion of the excited electron transfer over Ni- and Co -sulfide co-doped g-C3N4 photocatalyst (g-C3N4/NixCo1-xS2) for hydrogen Production under visible light irradiation".Scientific Reports 7(2017):7710(1-10). |
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