Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen
Wang YG(王圆广)1,2; Meng X(孟旭)1; Chen GX(陈革新)1; Zhao PQ(赵培庆)1; Zhao PQ(赵培庆)
刊名Catalysis Communications
2018
卷号104期号:0页码:106-111
关键词Heterogeneous Catalysis Green Oxidant Oms-2 Catalytic Oxidation Quinazolinones
ISSN号1566-7367
DOI10.1016/j.catcom.2017.10.024
英文摘要

Copper hydroxide supported on manganese oxide octahedral molecular sieves (Cu(OH)X/OMS-2) was prepared and was found to be highly active for the oxidative cyclization of benzyl alcohols or methylarenes solely with anthranilamides using oxygen as oxidant. The low loading copper hydroxide was used as a catalytic metal. The hydroxyl of catalyst with spherical agglomeration led to higher performance of catalytic activity for the synthesis of quinazolinones. Moreover, Cu(OH)X/OMS-2 could be reused 5 times without any significant loss of activity.

学科主题物理化学与绿色催化
资助项目催化新工艺研究组
语种英语
WOS记录号WOS:000423244900022
资助机构the National Natural Science Foundation of China (Grant Nos. 21403256 ; 21573261) ; the Suzhou Industrial Technology and Innovation Project (Grant No. SYG201531)
内容类型期刊论文
源URL[http://ir.licp.ac.cn/handle/362003/22217]  
专题兰州化学物理研究所_ERC国家工程研究中心
兰州化学物理研究所_OSSO国家重点实验室
兰州化学物理研究所_苏州研究院
通讯作者Zhao PQ(赵培庆)
作者单位1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China
2.University of Chinese Academy of Sciences, Beijing 100049, China
推荐引用方式
GB/T 7714
Wang YG,Meng X,Chen GX,et al. Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen[J]. Catalysis Communications,2018,104(0):106-111.
APA Wang YG,Meng X,Chen GX,Zhao PQ,&Zhao PQ.(2018).Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen.Catalysis Communications,104(0),106-111.
MLA Wang YG,et al."Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen".Catalysis Communications 104.0(2018):106-111.
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