The off-stoichiometry effect on the optical properties of water-soluble copper indium zinc sulfide quantum dots

doi:10.1016/j.jcis.2017.02.049

	The off-stoichiometry effect on the optical properties of water-soluble copper indium zinc sulfide quantum dots
	Xu, Yanqiao 1; Chen, Ting 1,2; Hu, Xiaobo 1; Jiang, Wan 2,3; Wang, Lianjun 2,3; Jiang, Weihui 1,2; Liu, Jianmin 2
刊名	Journal of Colloid and Interface Science
	2017
卷号	496 页码:479-486
ISSN号	00219797
DOI	10.1016/j.jcis.2017.02.049
英文摘要	Cu[sbnd]In[sbnd]Zn[sbnd]S quantum dots (CIZS QDs) were prepared via reflux method in aqueous solution using CuCl2·2H2O, InCl3·4H2O, Zn(OAc)2·2H2O and Na2S·9H2O as raw materials, L-glutathione (GSH) and sodium citrate (SC) as stabilizing agents, respectively. The effects of off-stoichiometry (Cu/In and Zn/Cu ratios) on the crystal structure and morphology were systematically studied by means of X-ray diffraction (XRD) and high-resolution transmission electron microscope (HRTEM), and the relative optical properties were also investigated by absorption and fluorescence spectra. The as-prepared water-dispersible CIZS QDs were around 3–4 nm and possessed the tetragonal chalcopyrite crystal structure. The photoluminescence (PL) intensity of QDs was significantly increased with decreasing the Cu/In ratio. Compared with the Cu/In ratio variation, changing Zn/Cu ratio was an effective strategy to realize a more uniform irradiation and a wide range of emission wavelength tunability. © 2017 Elsevier Inc.
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/25915]
专题	中国科学院上海硅酸盐研究所
作者单位	1.School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen; 333001, China; 2.National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen; 333001, China; 3.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai; 201620, China
推荐引用方式 GB/T 7714	Xu, Yanqiao,Chen, Ting,Hu, Xiaobo,et al. The off-stoichiometry effect on the optical properties of water-soluble copper indium zinc sulfide quantum dots[J]. Journal of Colloid and Interface Science,2017,496:479-486.
APA	Xu, Yanqiao.,Chen, Ting.,Hu, Xiaobo.,Jiang, Wan.,Wang, Lianjun.,...&Liu, Jianmin.(2017).The off-stoichiometry effect on the optical properties of water-soluble copper indium zinc sulfide quantum dots.Journal of Colloid and Interface Science,496,479-486.
MLA	Xu, Yanqiao,et al."The off-stoichiometry effect on the optical properties of water-soluble copper indium zinc sulfide quantum dots".Journal of Colloid and Interface Science 496(2017):479-486.