Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural

CORC > 青海盐湖研究所 > 中国科学院青海盐湖研究所 > 青海盐湖研究所知识仓储

	Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural
	Liu, Yong 1; Li, Zili 1; You, Yaohui 1; Zheng, Xiaogang 1; Wen, Jing 2
刊名	RSC ADVANCES
	2017
卷号	7 期号:81 页码:51281-51289
文献子类	Article
英文摘要	FePO4 catalysts with branch-like, flower-like, and spherical morphologies were synthesized for the conversion of methyl cellulose to 5-hydroxymethylfurfural (5-HMF) via a hydrothermal route. The molar ratio of Fe3+ and H2PO4- ions in the reaction system played a crucial role in the morphology of FePO4. Compared with flower-like, spherical and amorphous FePO4, branch-like FePO4 presented a better catalytic performance in the cellulose conversion and 5-HMF yield. The branch-like FePO4 retained a branch structure after recycling five times in the bi-phasic reaction process. The insolubility of low temperature and partial dissolution of elevated temperature were responsible for the excellent catalytic activity of the FePO4 phase-change catalyst. The combined effect of H+ ions and iron species generated from the hydrolysis of FePO4 can be favorable for the enhanced yield of 5-HMF.
WOS关键词	BRONSTED ACID CATALYSTS ; IONIC-LIQUID-MIXTURES ; EFFICIENT CONVERSION ; FRUCTOSE CONVERSION ; LEVULINIC ACID ; GLUCOSE DEHYDRATION ; DIMETHYL-SULFOXIDE ; AMORPHOUS FEPO4 ; LEWIS ; OXIDE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000414780700024
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6274]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源与化学实验室
作者单位	1.Neijiang Normal Univ, Coll Chem & Chem Engn, Neijiang 641100, Sichuan, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China
推荐引用方式 GB/T 7714	Liu, Yong,Li, Zili,You, Yaohui,et al. Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(81):51281-51289.
APA	Liu, Yong,Li, Zili,You, Yaohui,Zheng, Xiaogang,&Wen, Jing.(2017).Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural.RSC ADVANCES,7(81),51281-51289.
MLA	Liu, Yong,et al."Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural".RSC ADVANCES 7.81(2017):51281-51289.