A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids

doi:10.1177/0003702818773117

	A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids
	Xi, Shichuan 1,2,3,4; Zhang, Xin 1,2,3,4; Luan, Zhendong 1,2; Du, Zengfeng 1,2; Li, Lianfu 1,2,4; Wang, Bing 1,2,4; Cao, Lei 1,2; Lian, Chao 1,2; Yan, Jun 1,2
刊名	APPLIED SPECTROSCOPY
	2018-08-01
卷号	72 期号:8 页码:1234-1243
关键词	Quantitative analysis acid sulfate bisulfate concentration Raman spectroscopy
ISSN号	0003-7028
DOI	10.1177/0003702818773117
英文摘要	Raman spectroscopy has been applied to the quantitative analysis of the concentration of bisulfate in acid-sulfate fluids at different temperatures. The quantitative analysis method is based on the peak area ratios of HSO4-(v(1)) and H2O(v(2)), where PA(HSO4-/H2O) = [HSO4-] x (0.0066 x T+ 1.3070) at a temperature range of 0-100 degrees C. We found that the molal scattering coefficient of bisulfate increases slightly at the elevated temperature may be due to the changes of fraction of water molecules that are hydrogen-bonded. The method can also be applied to analyze physicochemical parameters of other acid fluids, such as hydrogen phosphate, bicarbonate, etc., and especially to the in situ detection of deep sea acid-sulfate hydrothermal fluids in the future.
资助项目	National Natural Science Foundation of China[41576104] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC004] ; Strategic Priority Research Program, CAS[XDA11040301] ; Strategic Priority Research Program, CAS[XDA11030301] ; Open Research Project of National Major Science & Technology Infrastructure (RV KEXUE)[NMSTI-KEXUE2017K01] ; NSFC-Shandong Joint Fund for Marine Science Research Centers[U1606401] ; National Key R&D Program of China[2016YFC0302103] ; Taishan Scholar Project Funding[tspd20161007]
WOS关键词	2ND DISSOCIATION-CONSTANT ; AQUEOUS SULFURIC-ACID ; PAPUA-NEW-GUINEA ; PORE-WATER ; CO2 SOLUBILITY ; SPECTROSCOPY ; PH ; IDENTIFICATION ; GEOCHEMISTRY ; TEMPERATURES
WOS研究方向	Instruments & Instrumentation ; Spectroscopy
语种	英语
出版者	SAGE PUBLICATIONS INC
WOS记录号	WOS:000440337500009
资助机构	National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Strategic Priority Research Program, CAS ; Open Research Project of National Major Science & Technology Infrastructure (RV KEXUE) ; NSFC-Shandong Joint Fund for Marine Science Research Centers ; National Key R&D Program of China ; Taishan Scholar Project Funding
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/11975]
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Zhang, Xin
作者单位	1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Geol & Environm, Qingdao, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res, Qingdao, Peoples R China 3.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Geol, Qingdao, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Xi, Shichuan,Zhang, Xin,Luan, Zhendong,et al. A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids[J]. APPLIED SPECTROSCOPY,2018,72(8):1234-1243.
APA	Xi, Shichuan.,Zhang, Xin.,Luan, Zhendong.,Du, Zengfeng.,Li, Lianfu.,...&Yan, Jun.(2018).A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids.APPLIED SPECTROSCOPY,72(8),1234-1243.
MLA	Xi, Shichuan,et al."A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids".APPLIED SPECTROSCOPY 72.8(2018):1234-1243.