SiO2-Modified Al2O3@AI-Supported Cobalt for Fischer-Tropsch Synthesis: Improved Catalytic Performance and Intensified Heat Transfer

doi:10.1021/acs.iecr.8b02842

	SiO2-Modified Al2O3@AI-Supported Cobalt for Fischer-Tropsch Synthesis: Improved Catalytic Performance and Intensified Heat Transfer
	Wang, Da 1,2; Wang, Zhong 1; Li, Guangci 1; Li, Xuebing 1; Hou, Bo 2
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2018-09-26
卷号	57 期号:38 页码:12756-12765
ISSN号	0888-5885
DOI	10.1021/acs.iecr.8b02842
英文摘要	SiO2-modified high thermal conductivity Al2O3@Al composites were synthesized and supported cobalt for Fischer-Tropsch synthesis to improve the catalytic performance and intensify the heat transfer within a fixed bed reactor. FTS results showed that the CO conversion and C5+ selectivity increased whereas CH4 selectivity decreased, which could be attributed to the reduced metal-support interaction via modification of SiO2 on the surface of Al2O3@Al. The heat transfer coefficients of the Co/SAl2O3@Al-x were more than 30 times those of conventional Co/Al2O3 according to the laser flash measurement. The thermal conductive study showed that a homogeneous radial temperature gradient was maintained within the catalyst bed for Co/SAl2O3@Al-x even without using a heat diluter, indicating good thermal conductivity within the reactor. In addition, the temperature of the catalyst bed for Co/SAl2O3@Al-x was easier to reach a "steady state" compared to the reactor packed with traditional low thermal conductive Co/Al2O3, which could improve the operating flexibility of FTS.
资助项目	National Natural Science Foundation of China[21808235]
WOS关键词	SUPPORTED COBALT ; HYDROTHERMAL OXIDATION ; CO HYDROGENATION ; SELECTIVITY ; CONDUCTIVITY ; REACTORS ; POROSITY ; DESIGN ; CARBON ; FUELS
WOS研究方向	Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000446142600014
资助机构	National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/11626]
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Li, Xuebing; Hou, Bo
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
推荐引用方式 GB/T 7714	Wang, Da,Wang, Zhong,Li, Guangci,et al. SiO2-Modified Al2O3@AI-Supported Cobalt for Fischer-Tropsch Synthesis: Improved Catalytic Performance and Intensified Heat Transfer[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(38):12756-12765.
APA	Wang, Da,Wang, Zhong,Li, Guangci,Li, Xuebing,&Hou, Bo.(2018).SiO2-Modified Al2O3@AI-Supported Cobalt for Fischer-Tropsch Synthesis: Improved Catalytic Performance and Intensified Heat Transfer.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(38),12756-12765.
MLA	Wang, Da,et al."SiO2-Modified Al2O3@AI-Supported Cobalt for Fischer-Tropsch Synthesis: Improved Catalytic Performance and Intensified Heat Transfer".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.38(2018):12756-12765.