Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites

doi:10.1016/j.envpol.2018.09.068

	Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites
	Liu, Aifeng 1; Zhao, Zongshan 1; Qu, Guangbo 2; Shen, Zhaoshuang 1; Shi, Jianbo 2,3; Jiang, Guibin 2
刊名	ENVIRONMENTAL POLLUTION
	2018-12-01
卷号	243 页码:1141-1153
关键词	TBBPA TBBPA derivatives Degradation Transformation Decomposition
ISSN号	0269-7491
DOI	10.1016/j.envpol.2018.09.068
英文摘要	Although the abiotic and biotic transformation/degradation (T/D) processes of tetrabromobisphenol A (TBBPA) have been widely investigated in model experiments, few reviews have focused on these processes along with their metabolites or degradation products. In this paper, we summarize the current knowledge on the T/D of TBBPA and its derivatives, including abiotic and biotic T/D strategies/conditions, mechanisms, metabolites and environmental occurrences. Various treatments, such as pyrolysis, photolysis, chemical reactions and biotransformation, have been employed to study the metabolic mechanism of TBBPA and its derivatives and to remediate associated contaminated environments. To date, more than 100 degradation products and metabolites have been identified, dominated by less brominated compounds such as bisphenol A, 2,6-dibromo-4-isopropylphenol, 2,6-dibromo-4-hydroxylphenol, 2,6-dibromophenol, isopropylene-2,6-dibromophenol, 4-(2-hydroxyisopropyl)-2,6-dibromophenol, etc. It can be concluded that the T/D of TBBPA mainly takes place through debromination and beta-scission. In some environmental media and human and animal tissues, brominated metabolites, glucoside and sulfate derivatives are also important T/D products. Here, the T/D products of TBBPA and its derivatives have been most comprehensively presented from the literature in recent 20 years. This review will enhance the understanding of the environmental behaviors of TBBPA-associated brominated flame retardants along with their ecological and health risks. (C) 2018 Elsevier Ltd. All rights reserved.
资助项目	National Natural Science Foundation of China[21707148] ; National Natural Science Foundation of China[21527901] ; China Postdoctoral Science Foundation[2018T110715] ; China Postdoctoral Science Foundation[2016M602210]
WOS关键词	BROMINATED FLAME RETARDANTS ; POLYBROMINATED DIPHENYL ETHERS ; PRINTED-CIRCUIT BOARDS ; JAPANESE BREAST-MILK ; BISPHENOL-A ; THERMAL-DEGRADATION ; RIVER SEDIMENT ; PHOTOCATALYTIC DEGRADATION ; REDUCTIVE DEHALOGENATION ; ANAEROBIC DEGRADATION
WOS研究方向	Environmental Sciences & Ecology
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000449892700039
资助机构	National Natural Science Foundation of China ; China Postdoctoral Science Foundation
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/11046]
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Zhao, Zongshan
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 3.Jianghan Univ, Inst Environm & Hlth, Wuhan 430056, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,et al. Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites[J]. ENVIRONMENTAL POLLUTION,2018,243:1141-1153.
APA	Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,Shen, Zhaoshuang,Shi, Jianbo,&Jiang, Guibin.(2018).Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites.ENVIRONMENTAL POLLUTION,243,1141-1153.
MLA	Liu, Aifeng,et al."Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites".ENVIRONMENTAL POLLUTION 243(2018):1141-1153.