Achieving photocatalytic water oxidation on LaNbON2 under visible light irradiation
Wan, Lipeng; Yang, Minghui; Li, Yue; Che, Ruxin; Zhang, Bingxue; Xiong, Feng-Qiang
刊名JOURNAL OF ENERGY CHEMISTRY
2018
卷号27期号:2页码:367-371
关键词Photoanodes Performance Latio2n Density
英文摘要LaNbON2 has narrow bandgap and wide visible-light absorption band, yet no photocatalytic water oxidation on LaNbON2 has been reported. By a post-annealing treatment in Ar, anion vacancies were brought into LaNbON2 as shown by EPR spectroscopy. These could act as donors in the semiconductor. And consequently the oxidative power of holes was enhanced as indicated by the difference between fermi level and valence band maximum (EF-EVBM) evaluated from valence band XPS. The annealed LaNbON2 photocatalyst acquired water oxidation ability for the first time, which was improved by combining CoOx as cocatalyst. Annealed LaNbON2 derived from La3NbO7 had smaller particle size, higher concentration of anion vacancies, bigger EF-EVBM and better performance for photocatalytic oxygen evolution reaction than LaNbON2 derived from LaNbO4. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
学科主题Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
公开日期2018-12-04
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/16786]  
专题2018专题
推荐引用方式
GB/T 7714
Wan, Lipeng,Yang, Minghui,Li, Yue,et al. Achieving photocatalytic water oxidation on LaNbON2 under visible light irradiation[J]. JOURNAL OF ENERGY CHEMISTRY,2018,27(2):367-371.
APA Wan, Lipeng,Yang, Minghui,Li, Yue,Che, Ruxin,Zhang, Bingxue,&Xiong, Feng-Qiang.(2018).Achieving photocatalytic water oxidation on LaNbON2 under visible light irradiation.JOURNAL OF ENERGY CHEMISTRY,27(2),367-371.
MLA Wan, Lipeng,et al."Achieving photocatalytic water oxidation on LaNbON2 under visible light irradiation".JOURNAL OF ENERGY CHEMISTRY 27.2(2018):367-371.
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