Butterfly Effect from finite dope chemical composition variations on the water/oil separation capabilities of super rough polyvinylidene difluoride (PVDF) porous membranes

CORC > 宁波材料技术与工程研究所 > 中国科学院宁波材料技术与工程研究所 > 2017专题

	Butterfly Effect from finite dope chemical composition variations on the water/oil separation capabilities of super rough polyvinylidene difluoride (PVDF) porous membranes
	Gao, Ailin; Yang, Qing; Xue, Lixin
刊名	JOURNAL OF MEMBRANE SCIENCE
	2017
卷号	524 页码:197-204
ISSN号	0376-7388
英文摘要	Polyvinylidene fluoride (PVDF) porous membranes with superwetting amphophilic surfaces were prepared by in situ cross-linking polymerization of varied triethoxyvinylsilane (VTES) and N-vinyl-2-pyrrolidone (VP) composition ratios during none-solvent induced phase separation (NIPS) processes, utilizing template stripping method. The extreme powers of surface roughness, in amplifying the finite differences in chemical composition of initial dope solution to the properties of the resulted membranes, were revealed by comparing the structures and surface properties of these membranes with super rough surfaces, to their analogues with medium-rough surfaces and films with smooth surfaces. "Butterfly Effect" was observed on the water/oil separation capability of the formed PVDF membranes from the finite variation on the initial chemical composition caused by the change of VTES/VP molar ratio in the dope solution from 0 to 0.33, 0.38, 0.43, 0.48 and 0.53. Huge variations in the oil and water fluxes and removal efficiencies in separating water-in-oil and oil-in-water emulsions of the formed membranes from the "Butterfly Effect" were studied relating to their differences in water-in-air contact angles, oil-in-air contact angles, oil-in-water contact angles and water-in-oil contact angles as well as pore sizes and surface roughness.
公开日期	2017-12-25
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/13987]
专题	2017专题
推荐引用方式 GB/T 7714	Gao, Ailin,Yang, Qing,Xue, Lixin. Butterfly Effect from finite dope chemical composition variations on the water/oil separation capabilities of super rough polyvinylidene difluoride (PVDF) porous membranes[J]. JOURNAL OF MEMBRANE SCIENCE,2017,524:197-204.
APA	Gao, Ailin,Yang, Qing,&Xue, Lixin.(2017).Butterfly Effect from finite dope chemical composition variations on the water/oil separation capabilities of super rough polyvinylidene difluoride (PVDF) porous membranes.JOURNAL OF MEMBRANE SCIENCE,524,197-204.
MLA	Gao, Ailin,et al."Butterfly Effect from finite dope chemical composition variations on the water/oil separation capabilities of super rough polyvinylidene difluoride (PVDF) porous membranes".JOURNAL OF MEMBRANE SCIENCE 524(2017):197-204.