Single Crystal Structure Study of Type I Clathrate K8Zn4Sn42 and K8In8Sn38
Heguri, Satoshi; Liu, Guo-Qiang; Jiang, Jun; Jiang, Haochuan; Tanigaki, Katsumi; Xu, Jingtao; Wu, Jiazhen; Tanabe, Yoichi
刊名JOURNAL OF ELECTRONIC MATERIALS
2017
卷号46期号:5页码:2765-2769
ISSN号0361-5235
英文摘要Single crystals of type I clathrate and were grown by the flux method. The structure properties of both clathrates were investigated by single-crystal x-ray diffraction. Both clathrates crystallize in space group , and no phase transition was observed in the investigated temperature range (100 K-450 K). The Debye temperature, the Einstein temperature, and the static disorder parameters of each clathrate were derived. The spread of the Einstein temperatures for , , and suggest that the charge distribution on the cage framework is crucial to the energy of rattling mode in the tetrakaidecahedron of the type-I clathrate.
公开日期2017-12-25
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/13866]  
专题2017专题
推荐引用方式
GB/T 7714
Heguri, Satoshi,Liu, Guo-Qiang,Jiang, Jun,et al. Single Crystal Structure Study of Type I Clathrate K8Zn4Sn42 and K8In8Sn38[J]. JOURNAL OF ELECTRONIC MATERIALS,2017,46(5):2765-2769.
APA Heguri, Satoshi.,Liu, Guo-Qiang.,Jiang, Jun.,Jiang, Haochuan.,Tanigaki, Katsumi.,...&Tanabe, Yoichi.(2017).Single Crystal Structure Study of Type I Clathrate K8Zn4Sn42 and K8In8Sn38.JOURNAL OF ELECTRONIC MATERIALS,46(5),2765-2769.
MLA Heguri, Satoshi,et al."Single Crystal Structure Study of Type I Clathrate K8Zn4Sn42 and K8In8Sn38".JOURNAL OF ELECTRONIC MATERIALS 46.5(2017):2765-2769.
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