B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity

doi:10.1002/ejic.201701206

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	B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity
	Zhang, Zejun 1,2; Zhang, Yanqiang 1,3; Li, Zhimin 1; Jiao, Nianming 1,2; Liu, Long 1,4; Zhang, Suojiang 1
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2018-02-28
期号	8 页码:981-986
关键词	Propellants Hypergolic Fuels Transition Metals Ionic Liquids Boron
ISSN号	1434-1948
DOI	10.1002/ejic.201701206
文献子类	Article
英文摘要	In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122- were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8-286.3 degrees C; densities: 1.215-1.264 gcm(-3)). The results demonstrate their promising applications in bipropellant formulations.
WOS关键词	Energetic Ionic Liquids ; Ignition-delay Times ; Rocket Fuels ; Hydrazine Derivatives ; Replacements ; Oxidizers ; Chemistry ; Fluids
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000426501400003
资助机构	National Natural Science Foundation of China(21576270 ; National Key Research and Development Program of China(2016YFB0600903) ; 21676281)
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/24022]
专题	过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位	1.Chinese Acad Sci, Div Ion Liquids & Green Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Henan, Peoples R China 4.Lab Particle Sci & Engn, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zejun,Zhang, Yanqiang,Li, Zhimin,et al. B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2018(8):981-986.
APA	Zhang, Zejun,Zhang, Yanqiang,Li, Zhimin,Jiao, Nianming,Liu, Long,&Zhang, Suojiang.(2018).B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(8),981-986.
MLA	Zhang, Zejun,et al."B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .8(2018):981-986.