High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor | |
Fu, Zhaolin1,2; Wang, Ze1,2; Lin, Weigang1,2,3; Song, Wenli1,2; Li, Songgeng1,2 | |
刊名 | APPLIED CATALYSIS A-GENERAL |
2017-10-25 | |
卷号 | 547页码:248-255 |
关键词 | Furfural Hydrogenation 2-methylfuran Hydrogen Donor Bimetallic Catalyst |
ISSN号 | 0926-860X |
DOI | 10.1016/j.apcata.2017.09.011 |
文献子类 | Article |
英文摘要 | Conversion of furfural to 2-methylfuran over Cu/Al2O3, Ni/Al2O3 and Ni-Cu/Al2O3 catalysts were investigated with formic acid as a hydrogen donor. Ni/Al2O3 showed a high catalytic activity but a moderate selectivity to 2-methylfuran. Contrarily, Cu/Al2O3 showed a low catalytic activity but a high selectivity for carbonyl reduction. Over the bimetallic catalysts Ni-10%Cu/Al2O3, by increasing Ni content, more furfural was converted with the reduction of carbonyl primarily. The effect of reaction solvent and the fraction of formic acid were also studied. The result showed that isopropanol solvent could contribute to the formation of furfuryl alcohol with 96% selectivity through the transfer hydrogenation process. Formic acid could decompose to H-2 and CO2, remarkably promoting the hydrogenolysis of furfuryl alcohol to 2-methylfuran. Finally, 100% conversion and 92 mol% yield of 2-methylfuran could be obtained over 10%Ni-10%Cu/Al2O3. It was attributed to the synergic effect of Ni-Cu metals, with increased affinity for carbonyl reduction. |
WOS关键词 | Situ Generated Hydrogen ; Ni-cu Catalysts ; Bio-oil ; Transfer Hydrogenation/hydrogenolysis ; Selective Hydrogenation ; Bimetallic Catalysts ; Phase Hydrogenation ; Pd Catalysts ; Reduction ; Glycerol |
WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
语种 | 英语 |
WOS记录号 | WOS:000413607100028 |
资助机构 | National Natural Science Foundation of China(51476180) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/23298] |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China 3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark |
推荐引用方式 GB/T 7714 | Fu, Zhaolin,Wang, Ze,Lin, Weigang,et al. High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor[J]. APPLIED CATALYSIS A-GENERAL,2017,547:248-255. |
APA | Fu, Zhaolin,Wang, Ze,Lin, Weigang,Song, Wenli,&Li, Songgeng.(2017).High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor.APPLIED CATALYSIS A-GENERAL,547,248-255. |
MLA | Fu, Zhaolin,et al."High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor".APPLIED CATALYSIS A-GENERAL 547(2017):248-255. |
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