Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation

doi:10.1002/macp.201700275

	Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation
	Xu, Jiawei 4; Zhang, Chong 1; Qiu, Zexiong 3; Lei, Zhenyu 2; Chen, Bing 2; Jiang, Jia-Xing 1; Wang, Feng 4
刊名	MACROMOLECULAR CHEMISTRY AND PHYSICS
	2017-11-01
卷号	218 期号:22
关键词	Gas Adsorption Microporous Organic Polymers Separation Triphenylphosphine
ISSN号	1022-1352
DOI	10.1002/macp.201700275
文献子类	Article
英文摘要	Two kinds of novel triphenylphosphine-containing microporous organic polymers are designed and synthesized via palladium-catalyzed SonogashiraHagihara coupling condensation reaction of triphenylphosphine oxideand sulfide-based monomers with different arylethynylene linkers. The gas adsorption isotherms reveal that these polymers have strong binding affinity for CO2 with high CO2 adsorption capacity, although they have moderate Brunauer-Emmett-Teller surface area ranging from 684 to 883 m(2) g(-1). Among the resulting polymers, triphenylphosphine oxidetris(4-ethynylphenyl) amine exhibits the highest CO2 uptake capacity of 2.61 mmol g(-1) at 273 K and 1.13 bar with relatively high gas selectivity of 60.2 for CO2 over N-2 at 273 K.
WOS关键词	POROUS AROMATIC FRAMEWORKS ; CARBON-DIOXIDE CAPTURE ; CO2 CAPTURE ; BUILDING-BLOCKS ; SURFACE-AREA ; NETWORKS SYNTHESIS ; SELECTIVE UPTAKE ; SORPTION ; CONSTRUCTION ; ENHANCEMENT
WOS研究方向	Polymer Science
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000417214600004
资助机构	Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/12752]
专题	中国科学院武汉物理与数学研究所
通讯作者	Jiang, Jia-Xing; Wang, Feng
作者单位	1.Shaanxi Normal Univ, Sch Mat Sci & Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.Wuhan Univ Technol, Int Sch Mat Sci & Engn, Wuhan 430070, Peoples R China 4.Wuhan Inst Technol, Sch Chem Engn & Pharm, Key Lab Green Chem Proc, Minist Educ, Wuhan 430073, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jiawei,Zhang, Chong,Qiu, Zexiong,et al. Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2017,218(22).
APA	Xu, Jiawei.,Zhang, Chong.,Qiu, Zexiong.,Lei, Zhenyu.,Chen, Bing.,...&Wang, Feng.(2017).Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation.MACROMOLECULAR CHEMISTRY AND PHYSICS,218(22).
MLA	Xu, Jiawei,et al."Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation".MACROMOLECULAR CHEMISTRY AND PHYSICS 218.22(2017).