SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF CYCLOPALLADATED FERROCENYLKETIMINES

	SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF CYCLOPALLADATED FERROCENYLKETIMINES
	WU, YJ ; ZHU, Y ; YUAN, HZ ; MAO, XA ; HUO, SQ ; DU, CX
刊名	JOURNAL OF ORGANOMETALLIC CHEMISTRY
	1994-12-13
卷号	483 期号:1-2 页码:139-146
关键词	Iron Palladium Cyclometalation Ferrocene Imine
ISSN号	0022-328X
文献子类	Article
英文摘要	The reactions of ferrocenylketimines C5H5FeC5H4C(CH3)=NAr (Ar = a variety of substituted phenyls, 1-naphthyl and 2-naphthyl) with lithium tetrachloropalladate (II) in the presence of sodium acetate in methanol for about 20 h at room temperature and the treatment of the resulting products with triphenylphosphine lead to the five-membered cyclopalladated derivatives [PdCl {C5H5FeC5H3C(CH3)=NAr} (PPh3)]. The structures of these metallocycles have been confirmed by IR and H-1 NMR spectroscopies, and further by X-ray crystal structure determination of [PdCl {C5H5FeC5H3C(CH3)=N(C6H4-4-Cl)} (PPh3)]. The palladium atom shows the four-coordinate structure typical of palladium complex, and the Pd-N distance is 2.135 angstrom. The H-1 NMR spectra of [PdCl {C5H5FeC5H3C(CH3)=NAr} (PPh3)] (Ar = C6H4-2-Cl and 1-naphthyl) show that both compounds exist as a mixture of two isomers.
WOS关键词	PALLADIUM(II) COMPLEX ; METALATION REACTIONS ; CRYSTAL-STRUCTURE ; METALS ; BONDS
WOS研究方向	Chemistry
语种	英语
出版者	ELSEVIER SCIENCE SA LAUSANNE
WOS记录号	WOS:A1994PU32500018
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/12563]
专题	中国科学院武汉物理与数学研究所
作者单位	1.ZHENGZHOU UNIV,DEPT CHEM,ZHENGZHOU 450052,PEOPLES R CHINA 2.LANZHOU UNIV,NATL LAB APPL ORGAN CHEM,LANZHOU 730000,PEOPLES R CHINA 3.CHINESE ACAD SCI,WUHAN INST PHYS,MAGNET RESONANCE & ATOM & MOLEC PHYS LAB,WUHAN 340071,PEOPLES R CHINA
推荐引用方式 GB/T 7714	WU, YJ,ZHU, Y,YUAN, HZ,et al. SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF CYCLOPALLADATED FERROCENYLKETIMINES[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,1994,483(1-2):139-146.
APA	WU, YJ,ZHU, Y,YUAN, HZ,MAO, XA,HUO, SQ,&DU, CX.(1994).SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF CYCLOPALLADATED FERROCENYLKETIMINES.JOURNAL OF ORGANOMETALLIC CHEMISTRY,483(1-2),139-146.
MLA	WU, YJ,et al."SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF CYCLOPALLADATED FERROCENYLKETIMINES".JOURNAL OF ORGANOMETALLIC CHEMISTRY 483.1-2(1994):139-146.