Thermal behavior and Raman spectral characteristics of step-heatingperhydrous coal: Implications for thermal maturity process

doi:10.1016/j.jaap.2017.10.015

CORC > 地球环境研究所 > 中国科学院地球环境研究所 > 黄土与第四纪地质国家重点实验室（2010~）

	Thermal behavior and Raman spectral characteristics of step-heatingperhydrous coal: Implications for thermal maturity process
	Liu,Guijian ; Wu,D(Wu,Dun)2,3; Chen,BY(Chen,Binyu)2; Sun,RY(Sun,Ruoyu)4; Liu,GJ(Liu,Guijian)1,2
刊名	Journal of Analytical and Applied Pyrolysis
	2017-11
卷号	128 期号:2017 页码:143-155
关键词	Thermal Behavior Raman Spectroscopy Thermal Maturity Perhydrous Coal Step-heating
DOI	10.1016/j.jaap.2017.10.015
文献子类	期刊论文
英文摘要	Perhydrous coal (PHC) had been widely investigated; however, a systematic research on the relationship between the structure of PHC and its thermal reactivity was rarely reported in the previous studies. The PHC was widely developed in the Carboniferous-Permian coal-bearing strata in the northern and eastern regions of the Huainan coalfield. In this study, we chose No. 13-1 PHC as the research object. Based on the macroscopic observation of No. 13-1 PHC of the borehole #9-3 and its logging response, a typical PHC sample was selected and pyrolyzed using a thermogravimetric analyzer (TGA) to acquire a set of coal samples after pyrolysis with wide range of random vitrinite reflectance (% VRo) from 0.86 to 7.79%. The thermal evolution process of PHC before and after pyrolysis was investigated by atomic force microscopy (AFM) and Raman spectroscopy. Research results show that: 1) in the experimental temperature range, the reflectance (VRo) range of PHC varied greatly; 2) with the increase of pyrolysis temperature, the Raman spectra of PHC changed significantly in the D band of disordered structure and the G band of ordered structure and the orderliness of its macromolecule particle arrangement was increasing gradually; 3) the relationship between the thermal reactivity of PHC and its Raman structure parameters was established, the FWHM of G-band can be used as indicators of the degree of thermal evolution of PHC; 4) compared with the G FWHM of normal coal with different rank, the thermal reaction temperature of PHC was advanced. Under the premise of comparable reaction temperature, the thermal maturity of PHC was gradually higher than that of bituminous coal, and slightly lower than anthracite, indicating that the actual PHC thermal maturity was suppressed by a higher amount of hydrogen.
项目编号	41502152 ; 41173032 ; 41403076 ; 2016T90576 ; 2015M571940 ; 973 Program ; 2014CB238903
语种	英语
资助机构	National Natural ScienceFoundation of China ; National Natural ScienceFoundation of China ; ChinaPostdoctoral Science Foundation ; ChinaPostdoctoral Science Foundation ; National Basic Research Program of China ; National Basic Research Program of China
内容类型	期刊论文
源URL	[http://ir.ieecas.cn/handle/361006/5625]
专题	地球环境研究所_黄土与第四纪地质国家重点实验室（2010~）
通讯作者	Liu,Guijian
作者单位	1.State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi’an, Shaanxi 710075, China 2.School of Earth and Space Sciences, University of Science and Technology of China, CAS Key Laboratory of Crust-Mantle Materials and Environment, Hefei, Anhui230026, China 3.Exploration Research Institute, Anhui Provincial Bureau of Coal Geology, Hefei, Anhui 23008, China 4.Institute of Surface-Earth System Science, Tianjin University, Tianjin 300072, China
推荐引用方式 GB/T 7714	Liu,Guijian,Wu,D,Chen,BY,et al. Thermal behavior and Raman spectral characteristics of step-heatingperhydrous coal: Implications for thermal maturity process[J]. Journal of Analytical and Applied Pyrolysis,2017,128(2017):143-155.
APA	Liu,Guijian,Wu,D,Chen,BY,Sun,RY,&Liu,GJ.(2017).Thermal behavior and Raman spectral characteristics of step-heatingperhydrous coal: Implications for thermal maturity process.Journal of Analytical and Applied Pyrolysis,128(2017),143-155.
MLA	Liu,Guijian,et al."Thermal behavior and Raman spectral characteristics of step-heatingperhydrous coal: Implications for thermal maturity process".Journal of Analytical and Applied Pyrolysis 128.2017(2017):143-155.