Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides
Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.; Wei, W; Ji, JX; Du, FT; Yang, L; Chen, SY; Liang, W; Fu, Q; Yi, D
刊名TETRAHEDRON LETTERS
2017
卷号58期号:25页码:2417-2420
关键词Copper-catalysis One-pot Procedure Beta-ketophosphine Oxides Ketones Vinylhydrazinedicarboxylates
DOI10.1016/j.tetlet.2017.05.005
产权排序1
文献子类Article
英文摘要A facile and efficient copper catalyzed one-pot method has been developed for the formation of beta-ketophosphine oxides from ketones and H-phosphine oxides under air at room temperature, in which vinylhydrazinedicarboxylate was formed as the key intermediate. Preliminary mechanistic studies indicated that the reaction might involve a radical process and carbonyl oxygen atom of beta-ketophosphine oxides came from molecular oxygen. (C) 2017 Elsevier Ltd. All rights reserved.
学科主题Chemistry
语种英语
资助机构We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001]
内容类型期刊论文
源URL[http://210.75.237.14/handle/351003/29232]  
专题成都生物研究所_天然产物研究
通讯作者Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.
推荐引用方式
GB/T 7714
Wei, W ,Du, FT ,Wei, W,et al. Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides[J]. TETRAHEDRON LETTERS,2017,58(25):2417-2420.
APA Wei, W .,Du, FT .,Wei, W.,Ji, JX.,Du, FT.,...&Zhang, ZJ.(2017).Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides.TETRAHEDRON LETTERS,58(25),2417-2420.
MLA Wei, W ,et al."Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides".TETRAHEDRON LETTERS 58.25(2017):2417-2420.
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