Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides | |
Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.; Wei, W; Ji, JX; Du, FT; Yang, L; Chen, SY; Liang, W; Fu, Q; Yi, D | |
刊名 | TETRAHEDRON LETTERS |
2017 | |
卷号 | 58期号:25页码:2417-2420 |
关键词 | Copper-catalysis One-pot Procedure Beta-ketophosphine Oxides Ketones Vinylhydrazinedicarboxylates |
DOI | 10.1016/j.tetlet.2017.05.005 |
产权排序 | 1 |
文献子类 | Article |
英文摘要 | A facile and efficient copper catalyzed one-pot method has been developed for the formation of beta-ketophosphine oxides from ketones and H-phosphine oxides under air at room temperature, in which vinylhydrazinedicarboxylate was formed as the key intermediate. Preliminary mechanistic studies indicated that the reaction might involve a radical process and carbonyl oxygen atom of beta-ketophosphine oxides came from molecular oxygen. (C) 2017 Elsevier Ltd. All rights reserved. |
学科主题 | Chemistry |
语种 | 英语 |
资助机构 | We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] |
内容类型 | 期刊论文 |
源URL | [http://210.75.237.14/handle/351003/29232] |
专题 | 成都生物研究所_天然产物研究 |
通讯作者 | Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China. |
推荐引用方式 GB/T 7714 | Wei, W ,Du, FT ,Wei, W,et al. Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides[J]. TETRAHEDRON LETTERS,2017,58(25):2417-2420. |
APA | Wei, W .,Du, FT .,Wei, W.,Ji, JX.,Du, FT.,...&Zhang, ZJ.(2017).Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides.TETRAHEDRON LETTERS,58(25),2417-2420. |
MLA | Wei, W ,et al."Copper catalyzed one-pot synthesis of beta-ketophosphine oxides from ketones and H-phosphine oxides".TETRAHEDRON LETTERS 58.25(2017):2417-2420. |
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