Copper-catalyzed direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen: A convenient approach to -ketophosphine oxides

doi:10.1080/00397911.2016.1205196

	Copper-catalyzed direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen: A convenient approach to -ketophosphine oxides
	Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.; Zhong, WW; Zhang, Q; Li, MS; Hu, DY; Cheng, M; Du, FT; Ji, JX; Wei, W; Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.
刊名	SYNTHETIC COMMUNICATIONS
	2016
卷号	46 期号:16 页码:1377-1385
DOI	10.1080/00397911.2016.1205196
产权排序	1
文献子类	Article
英文摘要	A simple and facile copper-catalyzed synthesis of -ketophosphine oxides via direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen has been developed under mild conditions without any base or cocatalyst. A radical reaction pathway for the formation of -ketophosphine oxides is proposed. An O-18 labeling experiment suggested that the carbonyl oxygen atom of -ketophosphine oxides originated from dioxygen. [GRAPHICS] .
学科主题	Chemistry
语种	英语
资助机构	National Natural Science Foundation of China [21172213, 21302109, 21402184, 21572217] ; National Natural Science Foundation of China [21172213, 21302109, 21402184, 21572217] ; Natural Science Foundation of Shandong Province [ZR2015JL004] ; Natural Science Foundation of Shandong Province [ZR2015JL004] ; National Natural Science Foundation of China [21172213, 21302109, 21402184, 21572217] ; National Natural Science Foundation of China [21172213, 21302109, 21402184, 21572217] ; Natural Science Foundation of Shandong Province [ZR2015JL004] ; Natural Science Foundation of Shandong Province [ZR2015JL004]
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/28216]
专题	成都生物研究所_天然产物研究
通讯作者	Du, FT (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.; Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.
推荐引用方式 GB/T 7714	Du, FT ,Zhong, WW,Zhang, Q,et al. Copper-catalyzed direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen: A convenient approach to -ketophosphine oxides[J]. SYNTHETIC COMMUNICATIONS,2016,46(16):1377-1385.
APA	Du, FT .,Zhong, WW.,Zhang, Q.,Li, MS.,Hu, DY.,...&Wei, W .(2016).Copper-catalyzed direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen: A convenient approach to -ketophosphine oxides.SYNTHETIC COMMUNICATIONS,46(16),1377-1385.
MLA	Du, FT ,et al."Copper-catalyzed direct oxyphosphorylation of alkynes with H-phosphine oxides and dioxygen: A convenient approach to -ketophosphine oxides".SYNTHETIC COMMUNICATIONS 46.16(2016):1377-1385.