Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells

doi:10.1038/srep46724

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	Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells
	Yang, YG; Feng, SL; Li, M; Xu, WD; Yin, GZ; Wang, ZK; Sun, BQ; Gao, XY
刊名	SCIENTIFIC REPORTS
	2017
卷号	7 页码:-
ISSN号	2045-2322
DOI	10.1038/srep46724
文献子类	期刊论文
英文摘要	Using poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) as hole conductor, a series of inverted planar CH3NH3PbI3-xClx perovskite solar cells (PSCs) were fabricated based on perovskite annealed by an improved time-temperature dependent (TTD) procedure in a flowing nitrogen atmosphere for different time. Only after an optimum annealing time, an optimized power conversion efficiency of 14.36% could be achieved. To understand their performance dependence on annealing time, an in situ real-time synchrotron-based grazing incidence X-ray diffraction (GIXRD) was used to monitor a step-by-step gradual structure transformation from distinct mainly organicinorganic hybrid materials into highly ordered CH3NH3PbI3 crystal during annealing. However, a re-crystallization process of perovskite crystal was observed for the first time during such an annealing procedure, which helps to enhance the perovskite crystallization and preferential orientations. The present GIXRD findings could well explain the drops of the open circuit voltage (V-oc) and the fill factor (FF) during the ramping of temperature as well as the optimized power conversion efficiency achieved after an optimum annealing time. Thus, the present study not only illustrates clearly the decisive roles of post-annealing in the formation of solution-processed perovskite to better understand its formation mechanism, but also demonstrates the crucial dependences of device performance on the perovskite microstructure in PSCs.
语种	英语
WOS记录号	WOS:000399979800002
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/27256]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Yang, YG,Feng, SL,Li, M,et al. Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells[J]. SCIENTIFIC REPORTS,2017,7:-.
APA	Yang, YG.,Feng, SL.,Li, M.,Xu, WD.,Yin, GZ.,...&Gao, XY.(2017).Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells.SCIENTIFIC REPORTS,7,-.
MLA	Yang, YG,et al."Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells".SCIENTIFIC REPORTS 7(2017):-.