2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction

doi:10.1039/c6ta10261a

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction
	Huo, LL; Liu, BC; Zhang, G; Si, R; Liu, J; Zhang, J
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2017
卷号	5 期号:10 页码:4868-4878
ISSN号	2050-7488
DOI	10.1039/c6ta10261a
文献子类	期刊论文
英文摘要	Rational design of inexpensive, highly active, and long-term stable non-precious metal electrocatalysts for oxygen reduction reaction (ORR) is of significant importance for large-scale applications of fuel cells in practice. In this paper, we report, for the first time, the construction of 2D layered mesoporous transition metal-nitrogen-doped carbon/nitrogen-doped graphene (meso-M-N-C/N-G, M = Fe, Co, and Ni) electrocatalysts using 4,4-bipyridine as the nitrogen and carbon source and mesoporous KIT-6/N-G generated by in situ formation of KIT-6 on graphene nanosheets as a template. The meso-Fe-N-C/N-G electrocatalyst showed super electrocatalytic performance for ORR. Excitingly, its catalytic activity and durability were superior to those of Pt/C, making it a good candidate as an ORR electrocatalyst in fuel cells. The results suggested that the outstanding electrocatalytic performance of the electrocatalysts could be attributed to the unique mesoporous structure, high surface area, ultrasmall size of Fe or FeOx nanocrystals embedded in 2D layered N-G nanosheets, excellent electron transportation, homogeneous distribution of high-density pyridinic N and graphitic N, graphitic C, and abundant metal active sites (Fe-N-x). The synthesis approach can be used as a versatile route toward the construction of various 2D layered graphene-based mesoporous materials.
语种	英语
WOS记录号	WOS:000396146900015
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/27237]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Huo, LL,Liu, BC,Zhang, G,et al. 2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(10):4868-4878.
APA	Huo, LL,Liu, BC,Zhang, G,Si, R,Liu, J,&Zhang, J.(2017).2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction.JOURNAL OF MATERIALS CHEMISTRY A,5(10),4868-4878.
MLA	Huo, LL,et al."2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction".JOURNAL OF MATERIALS CHEMISTRY A 5.10(2017):4868-4878.