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Janus colloidal copolymers
Zhou, Peng; Liang, Fuxin; Liu, Yijiang; Deng, Renhua; Yang, Haili; Wang, Qian; Qu, Xiaozhong; Yang, Zhenzhong
刊名SCIENCE CHINA-MATERIALS
2015-12-01
卷号58期号:12页码:961-968
英文摘要We propose a new type of nanocomposite that we call Janus colloidal copolymers (JCCPs). JCCPs have two different polymers conjugated on opposite sides of a nanosized colloid. Janus clusters of copolymer PS-b-PAA (where PS is polystyrene and PAA is poly(acrylic acid)) are self-organized within confined mesoporous silica channels onto the surface of iron oxide (Fe3O4) core particles by coordination-induced adsorption. PS-cPAA diblock JCCPs are fabricated by selective crosslinking of the nanosized PAA domains. In addition, the crosslinked PAA domains are terminated with amine-capped polyethylene glycol (PEG) to form PS-cPAA-PEG triblock JCCPs. The cPAA domain containing functional groups can serve as a nanoreactor to allow in situ preparation of functional materials. The composite JCCPs combine the functionality of nanosized colloids with the amphiphilic performance and self-organization capability of copolymers.
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38657]  
专题化学研究所_其它
推荐引用方式
GB/T 7714
Zhou, Peng,Liang, Fuxin,Liu, Yijiang,et al. Janus colloidal copolymers[J]. SCIENCE CHINA-MATERIALS,2015,58(12):961-968.
APA Zhou, Peng.,Liang, Fuxin.,Liu, Yijiang.,Deng, Renhua.,Yang, Haili.,...&Yang, Zhenzhong.(2015).Janus colloidal copolymers.SCIENCE CHINA-MATERIALS,58(12),961-968.
MLA Zhou, Peng,et al."Janus colloidal copolymers".SCIENCE CHINA-MATERIALS 58.12(2015):961-968.
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