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Sulfur, Trace Nitrogen and Iron Codoped Hierarchically Porous Carbon Foams as Synergistic Catalysts for Oxygen Reduction Reaction
Guo, Zhaoyan; Jiang, Congcong; Teng, Chao; Ren, Guangyuan; Zhu, Ying; Jiang, Lei
刊名ACS APPLIED MATERIALS & INTERFACES
DEC 20 2014
卷号6期号:23页码:21454-21460
英文摘要Nickel oxide (NiO) is a promising electrode material for supercapacitors because of its low cost and high theoretical specific capacitance of 2573 F g(-1). However, the low electronic conductivity and poor cycling stability of NiO limit its practical applications. To overcome these limitations, an efficient atomic layer deposition (ALD) method is demonstrated here for the fabrication of NiO/nanoporous graphene (NG) composites as electrode materials for supercapacitors. ALD allows uniform deposition of NiO nanoparticles with controlled sizes on the surface of NG, thus offering a novel route to design NiO/NG composites for supercapacitor applications with high surface areas and greatly improved electrical conductivity and cycle stability. Electrochemical measurements reveal that the NiO/NG composites obtained by ALD exhibited excellent specific capacitance of up to similar to 1005.8 F g(-1) per mass of the composite electrode (the specific capacitance value is up to similar to 1897.1 F g(-1) based on the active mass of NiO), and stable performance after 1500 cycles. Furthermore, electrochemical performance of the NiO/NG composites is found to strongly depend on the size of NiO nanoparticles.
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38572]  
专题化学研究所_其它
推荐引用方式
GB/T 7714
Guo, Zhaoyan,Jiang, Congcong,Teng, Chao,et al. Sulfur, Trace Nitrogen and Iron Codoped Hierarchically Porous Carbon Foams as Synergistic Catalysts for Oxygen Reduction Reaction[J]. ACS APPLIED MATERIALS & INTERFACES,DEC ,6(23):21454-21460.
APA Guo, Zhaoyan,Jiang, Congcong,Teng, Chao,Ren, Guangyuan,Zhu, Ying,&Jiang, Lei.(DEC ).Sulfur, Trace Nitrogen and Iron Codoped Hierarchically Porous Carbon Foams as Synergistic Catalysts for Oxygen Reduction Reaction.ACS APPLIED MATERIALS & INTERFACES,6(23),21454-21460.
MLA Guo, Zhaoyan,et al."Sulfur, Trace Nitrogen and Iron Codoped Hierarchically Porous Carbon Foams as Synergistic Catalysts for Oxygen Reduction Reaction".ACS APPLIED MATERIALS & INTERFACES 6.23(DEC ):21454-21460.
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