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Vapor-Phase Selective Oxidation of Toluene Catalyzed by Graphitic Carbon Nitride Supported Vanadium Oxide
Huang, Zhijun; Yan, Fengwen; Yuan, Guoqing
刊名CATALYSIS LETTERS
2017-02-01
卷号147期号:2页码:509-516
关键词Graphitic Carbon Nitride Vanadium Oxide Toluene Vapor-phase Oxidation
英文摘要Organic materials have seldom been used in vapor-phase reaction due to their poor thermal stability. To solve this problem, toluene vapor-phase oxidation catalyst was fabricated by supporting vanadium oxide onto graphitic carbon nitride (g-C3N4), an organic material with excellent thermal and oxidative stability. The nitrogen-rich property provides g-C3N4 with abundant anchoring sites, leading to high dispersion of vanadium oxide. When used as catalysts for the oxidation of toluene, V-g-C3N4 exhibited greatly improved activity and selectivity to benzaldehyde compared to traditional catalyst. After the vapor-phase reaction at 330 A degrees C for 6 h, no marked deactivation was observed. The TGA, XRD, FT-IR and XPS results revealed that V-g-C3N4 keeps constant during this high-temperature process.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38204]  
专题化学研究所_绿色印刷实验室
作者单位Chinese Acad Sci, Inst Chem, Key Lab Green Printing, Beijing Natl Lab Mol Sci, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Huang, Zhijun,Yan, Fengwen,Yuan, Guoqing. Vapor-Phase Selective Oxidation of Toluene Catalyzed by Graphitic Carbon Nitride Supported Vanadium Oxide[J]. CATALYSIS LETTERS,2017,147(2):509-516.
APA Huang, Zhijun,Yan, Fengwen,&Yuan, Guoqing.(2017).Vapor-Phase Selective Oxidation of Toluene Catalyzed by Graphitic Carbon Nitride Supported Vanadium Oxide.CATALYSIS LETTERS,147(2),509-516.
MLA Huang, Zhijun,et al."Vapor-Phase Selective Oxidation of Toluene Catalyzed by Graphitic Carbon Nitride Supported Vanadium Oxide".CATALYSIS LETTERS 147.2(2017):509-516.
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