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Hydrogen-transfer conversion of furfural into levulinate esters as potential biofuel feedstock
Chen, Bingfeng; Li, Fengbo; Huang, Zhijun; Yuan, Guoqing
刊名JOURNAL OF ENERGY CHEMISTRY
2016-09-01
卷号25期号:5页码:888-894
关键词Furfural Bifunctional Catalyst Transfer Hydrogenation Solid Acid Levulinate Esters
英文摘要Furfural is directly converted to levulinate esters (isopropyl levulinate and furan-2-ylmethyl-levulinate) as potential biofuel feedstocks, through a combined catalytic strategy. Nb2O5-ZrO2 mixed oxide microspheres are used as bifunctional catalysts for hydrogen-transfer hydrogenation and acid-catalyzed alcoholysis in isopropanol. Bifunctional catalysts improve sustainability of furfural conversion through process intensification. Hydrogen transfer hydrogenation from isopropanol avoids dangerous hydrogen gas, and abates process and environmental costs. Isopropyl levulinate and furan-2-ylmethyl-levulinate are the main products that can be applied as blending components in biodiesel or hydrocarbon fuels. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B. V. and Science Press. All rights reserved.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/37981]  
专题化学研究所_绿色印刷实验室
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Green Printing, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,et al. Hydrogen-transfer conversion of furfural into levulinate esters as potential biofuel feedstock[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(5):888-894.
APA Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,&Yuan, Guoqing.(2016).Hydrogen-transfer conversion of furfural into levulinate esters as potential biofuel feedstock.JOURNAL OF ENERGY CHEMISTRY,25(5),888-894.
MLA Chen, Bingfeng,et al."Hydrogen-transfer conversion of furfural into levulinate esters as potential biofuel feedstock".JOURNAL OF ENERGY CHEMISTRY 25.5(2016):888-894.
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