Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres

	Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres
	Bin, De-Shan 1,2,3; Chi, Zi-Xiang 1,2; Li, Yutao 4,5; Zhang, Ke 3,6; Yang, Xinzheng 3,7; Sun, Yong-Gang 1,2,3; Piao, Jun-Yu 1,2,3; Cao, An-Min 1,2,3; Wan, Li-Jun 1,2,3
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2017-09-27
卷号	139 期号:38 页码:13492-13498
英文摘要	Hollow carbon nanostructures have inspired numerous interests in areas such as energy conversion/storage, biomedicine, catalysis, and adsorption. Unfortunately, their synthesis mainly relies on template-based routes, which include tedious operating procedures and showed inadequate capability to build complex architectures. Here, by looking into the inner structure of single polymeric nanospheres, we identified the complicated compositional chemistry underneath their uniform shape, and confirmed that nanoparticles themselves stand for an effective and versatile synthetic platform for functional hollow carbon architectures. Using the formation of 3-aminophenol/formaldehyde resin as an example, we were able to tune its growth kinetics by controlling the molecular/environmental variables, forming resin nanospheres with designated styles of inner constitutional inhomogeneity. We confirmed that this intraparticle difference could be well exploited to create a large variety of hollow carbon, architectures with desirable structural characters for their applications; for example, high-capacity anode for potassium-ion battery has been demonstrated with the multishelled hollow carbon nanospheres.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41231]
专题	化学研究所_高分子物理与化学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA 5.Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA 6.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 7.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Bin, De-Shan,Chi, Zi-Xiang,Li, Yutao,et al. Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(38):13492-13498.
APA	Bin, De-Shan.,Chi, Zi-Xiang.,Li, Yutao.,Zhang, Ke.,Yang, Xinzheng.,...&Wan, Li-Jun.(2017).Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(38),13492-13498.
MLA	Bin, De-Shan,et al."Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.38(2017):13492-13498.