Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior

	Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior
	Yuan, Shi-Fang 1; Duan, Ting 2; Wang, Lijing 2; Wei, Xuehong 1; Wang, Xinxin 3; Sun, Wen-Hua3
刊名	INORGANICA CHIMICA ACTA
	2017-09-01
卷号	466 页码:497-501
关键词	Azaallylzirconium Oxo-bridged Ethylene Polymerization Synthesis Characterization
英文摘要	The oxo-bridged azaallylzirconium chlorides (mu-O){eta(3)-(2,6-Et-2-4-R-C6H2) N(Ph) CCHSiMe2NMe2ZrCl2}(2), [R = Me (C1) and H (C2)] have been prepared in reasonable yields from the reactions of zirconium tetrachloride and the correspondent ligands, Me2NMe2SiCH2(Ph)CN(2,6-Et-2-4-R-C6H2). The representative complex C1 was crystallized and identified by the single-crystal X-ray diffraction, indicating oxo-bridged dinuclear azaallylzirconium structure. Both azaallylzirconium complexes exhibited notable catalytic activities toward ethylene polymerization in the presence of MAO, and obtained polyethylenes possess high molecular weights. (C) 2017 Elsevier B.V. All rights reserved.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41077]
专题	化学研究所_工程塑料实验室
作者单位	1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Shanxi, Peoples R China 2.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yuan, Shi-Fang,Duan, Ting,Wang, Lijing,et al. Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior[J]. INORGANICA CHIMICA ACTA,2017,466:497-501.
APA	Yuan, Shi-Fang,Duan, Ting,Wang, Lijing,Wei, Xuehong,Wang, Xinxin,&Sun, Wen-Hua.(2017).Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior.INORGANICA CHIMICA ACTA,466,497-501.
MLA	Yuan, Shi-Fang,et al."Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior".INORGANICA CHIMICA ACTA 466(2017):497-501.