Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step

	Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step
	Gong, Yuanzheng 1; Yang, Chun 1; Ji, Hongwei 1; Chen, Chuncheng 1; Ma, Wanhong 1,2; Zhao, Jincai 1,2
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2017-08-17
卷号	12 期号:16 页码:2048-2051
关键词	h(Vb)(+)/(Oh)-o-center Dot Oxidation Hydroxylation Of Aromatics Inverse Kinetic Isotope Effect Rate-determining Step Tio2 Photocatalysis
英文摘要	In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7-0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced h(vb)(+) can be the rate-determining step.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39315]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Key Lab Photochem, Natl Lab Mol Sci, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,et al. Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(16):2048-2051.
APA	Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,Chen, Chuncheng,Ma, Wanhong,&Zhao, Jincai.(2017).Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step.CHEMISTRY-AN ASIAN JOURNAL,12(16),2048-2051.
MLA	Gong, Yuanzheng,et al."Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step".CHEMISTRY-AN ASIAN JOURNAL 12.16(2017):2048-2051.