Microbial-Phosphorus-Enabled Synthesis of Phosphide Nanocomposites for Efficient Electrocatalysts

CORC > 化学研究所 > 中国科学院化学研究所 > 分子纳米结构与纳米技术实验室

	Microbial-Phosphorus-Enabled Synthesis of Phosphide Nanocomposites for Efficient Electrocatalysts
	Zhang, Tian-Qi 1,2; Liu, Jian 1,2; Huang, Lin-Bo 1,2; Zhang, Xu-Dong 1,2; Sun, Yong-Gang 1,2; Liu, Xiao-Chan 1,2; Bin, De-Shan 1,2; Chen, Xi 3; Cao, An-Min 1,2; Hu, Jin-Song 1,2
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2017-08-16
卷号	139 期号:32 页码:11248-11253
英文摘要	Transition-metal phosphides have recently been identified as low-cost and efficient electrocatalysts that are highly active for the hydrogen evolution reaction. Unfortunately, to achieve a controlled phosphidation of nonprecious metals toward a desired nanostructure of metal phosphides, the synthetic processes usually turned complicated, high-cost, and even dangerous due to the reaction chemistry related to different phosphorus sources. It becomes even more challenging when considering the. integration of those active metal phosphides with the structural engineering of their conductive matrix toward a favorable architecture for optimized catalytic performance. Herein, we identified that the biomass itself could act as an effective synthetic platform for the construction of supported metal phosphides by recovering its inner phosphorus upon reacting with transition-metals ions, forming well-dispersed, highly active nanoparticles of metal phosphides incorporated in the nanoporous carbon matrix, which promised high catalytic activity in the hydrogen evolution reaction. Our synthetic protocol not only provides a simple and effective strategy for the construction of a large variety of highly active nanoparticles of metal phosphides but also envisions new perspectives on an integrated utilization of the essential ingredients, particularly phosphorus, together with the innate architecture of the existing biomass for the creation of functional nanomaterials toward sustainable energy development.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39293]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Chinese Acad Sci ICCAS, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci UCAS, Beijing 100049, Peoples R China 3.Univ Sci & Technol China USTC, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Tian-Qi,Liu, Jian,Huang, Lin-Bo,et al. Microbial-Phosphorus-Enabled Synthesis of Phosphide Nanocomposites for Efficient Electrocatalysts[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(32):11248-11253.
APA	Zhang, Tian-Qi.,Liu, Jian.,Huang, Lin-Bo.,Zhang, Xu-Dong.,Sun, Yong-Gang.,...&Wan, Li-Jun.(2017).Microbial-Phosphorus-Enabled Synthesis of Phosphide Nanocomposites for Efficient Electrocatalysts.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(32),11248-11253.
MLA	Zhang, Tian-Qi,et al."Microbial-Phosphorus-Enabled Synthesis of Phosphide Nanocomposites for Efficient Electrocatalysts".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.32(2017):11248-11253.