Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex

	Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex
	Wang, Le 1,2; Lv, Jian 1,2,3; Zhang, Long 1,2,3; Luo, Sanzhong 1,2,3
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017-08-28
卷号	56 期号:36 页码:10867-10871
关键词	[4+2] Annulation Allenes Chiral Phosphates Homogeneous Catalysis Indium
英文摘要	Regio- and enantioselective [4+2] annulation between beta,gamma-unsaturated alpha-keto esters and non-activated allenes was achieved by using a chiral cationic indium(III)/phosphate catalyst. The reaction affords the corresponding C3-selective dihydropyrans in good yields and with high enantioselectivity (up to 99% ee).
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39269]
专题	化学研究所_分子识别与功能实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Wang, Le,Lv, Jian,Zhang, Long,et al. Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(36):10867-10871.
APA	Wang, Le,Lv, Jian,Zhang, Long,&Luo, Sanzhong.(2017).Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(36),10867-10871.
MLA	Wang, Le,et al."Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.36(2017):10867-10871.