Palladium-Catalyzed Si-C Bond Formation toward Sila-Annulated Perylene Diimides

	Palladium-Catalyzed Si-C Bond Formation toward Sila-Annulated Perylene Diimides
	Ma, Zetong 1,3; Xiao, Chengyi 2; Liu, Chunming 1; Meng, Dong 1; Jiang, Wei 1; Wang, Zhaohui 1
刊名	ORGANIC LETTERS
	2017-08-18
卷号	19 期号:16 页码:4331-4334
英文摘要	The first example of sila-annulation onto the perylene diimide core that allows the effective and practical synthesis of both sila- and disilaperylene diimides (Si-PDIs and 2Si-PDIs) in one pot through palladium-catalyzed SiC bond formation is presented. The corresponding sila-annulated perylene diimides demonstrated exceptional optical properties with noteworthy bathochromic shifts and excellent fluorescence quantum yields. Single crystal analysis revealed almost planar molecular structures and distinct packing arrangements with intense pi-pi interactions. Their single crystal OFET devices showed good electron mobilities of up to 0.3 cm(2) V-1 s(-1) under a nitrogen atmosphere.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39261]
专题	化学研究所_有机固体实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 2.Beijing Univ Chem Technol, Coll Energy, Beijing 100029, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ma, Zetong,Xiao, Chengyi,Liu, Chunming,et al. Palladium-Catalyzed Si-C Bond Formation toward Sila-Annulated Perylene Diimides[J]. ORGANIC LETTERS,2017,19(16):4331-4334.
APA	Ma, Zetong,Xiao, Chengyi,Liu, Chunming,Meng, Dong,Jiang, Wei,&Wang, Zhaohui.(2017).Palladium-Catalyzed Si-C Bond Formation toward Sila-Annulated Perylene Diimides.ORGANIC LETTERS,19(16),4331-4334.
MLA	Ma, Zetong,et al."Palladium-Catalyzed Si-C Bond Formation toward Sila-Annulated Perylene Diimides".ORGANIC LETTERS 19.16(2017):4331-4334.