Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals

	Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals
	Gong, Yanjun 1,3; Zhang, Yifan 4; Xiong, Wei 1,3; Zhang, Ke 2,3; Che, Yanke 1,3; Zhao, Jincai 1,3
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2017-08-09
卷号	139 期号:31 页码:10649-10652
英文摘要	In this work, we fabricated four diphenylcyclopropenone (DPCP) crystals, which involved various molecular interactions encoded in individual molecular structures 1-4. On the basis of crystalline structural analysis and photoresponsive characterization of the resultant single-crystal microribbons 1-4, we demonstrated that the magnitude of molecular interactions could effectively control the quantum chain reaction and the photoresponsive property of the DPCP crystals. The microribbons 1 and 2 having weak molecular interactions exhibited an efficient chain reaction and large mechanical photoresponses (i.e., photomelting and photodeforming), whereas the microribbons 3 and 4 with strong molecular interactions exhibited no chain reaction and mechanical morphology change. Our work presented a new way to achieve molecular crystals with enhanced mechanical photoresponses.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39200]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Ulsan Natl Inst Sci & Technol, IBS Ctr Soft & Living Matter, Ulsan 689789, South Korea
推荐引用方式 GB/T 7714	Gong, Yanjun,Zhang, Yifan,Xiong, Wei,et al. Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(31):10649-10652.
APA	Gong, Yanjun,Zhang, Yifan,Xiong, Wei,Zhang, Ke,Che, Yanke,&Zhao, Jincai.(2017).Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(31),10649-10652.
MLA	Gong, Yanjun,et al."Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.31(2017):10649-10652.