Reductive amination/cyclization of levulinic acid to pyrrolidones versus pyrrolidines by switching the catalyst from AlCl3 to RuCl3 under mild conditions

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	Reductive amination/cyclization of levulinic acid to pyrrolidones versus pyrrolidines by switching the catalyst from AlCl3 to RuCl3 under mild conditions
	Wu, Cailing 1,2; Luo, Xiaoying 1,2; Zhang, Hongye 1; Liu, Xinwei 1,2; Ji, Guipeng 1,2; Liu, Zhenghui 1,2; Liu, Zhimin 1,2
刊名	GREEN CHEMISTRY
	2017-08-07
卷号	19 期号:15 页码:3525-3529
英文摘要	Herein the reductive amination/cyclization of levulinic acid using phenylsilane was presented to selectively produce pyrrolidones versus pyrrolidines under mild conditions by switching the catalyst from AlCl3 to RuCl3. Using AlCl3 as the catalyst, pyrrolidones were solely obtained at room temperature, while RuCl3 as the catalyst selectively afforded pyrrolidines in high yields at 45 degrees C.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39196]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wu, Cailing,Luo, Xiaoying,Zhang, Hongye,et al. Reductive amination/cyclization of levulinic acid to pyrrolidones versus pyrrolidines by switching the catalyst from AlCl3 to RuCl3 under mild conditions[J]. GREEN CHEMISTRY,2017,19(15):3525-3529.
APA	Wu, Cailing.,Luo, Xiaoying.,Zhang, Hongye.,Liu, Xinwei.,Ji, Guipeng.,...&Liu, Zhimin.(2017).Reductive amination/cyclization of levulinic acid to pyrrolidones versus pyrrolidines by switching the catalyst from AlCl3 to RuCl3 under mild conditions.GREEN CHEMISTRY,19(15),3525-3529.
MLA	Wu, Cailing,et al."Reductive amination/cyclization of levulinic acid to pyrrolidones versus pyrrolidines by switching the catalyst from AlCl3 to RuCl3 under mild conditions".GREEN CHEMISTRY 19.15(2017):3525-3529.