BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet

	BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet
	Zhang, Bin 1,2; Zhang, Yan 3; Wang, Zheming 4; Gao, Zengqiang 5; Yang, Deliang 6,7; Wang, Dongwei 8; Guo, Yanjun 8; Zhu, Daoben 1,2
刊名	CHEMISTRYOPEN
	2017-06-01
卷号	6 期号:3 页码:320-324
关键词	Antiferromagnetism Cation Templates Charge-transfer Salts Jahn-teller Distortion Square Lattices
英文摘要	A dual-functional organic-inorganic hybrid (BEDTTTF) Cu-2(2)( HCOO) 5 ( 1) (BEDT-TTF=bis(ethylenedithio) tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper- formate framework [(C2H5)(3)NH](2)Cu-2(HCOO)(5) in a C6H5Cl-C2H5OH solution. Compound 1 was composed of organic donor BEDT-TTF+0.5 in a qphase arrangement and Jahn- Teller distorted (4,4) grid anion sheets [Cu-2(HCOO)(5)-]n with S=1/2. We identified the material as a semiconductor with values of sigma 300K= 10(-1) Scm(-1). The anion sheet is a coordination isomer of [Cu-2(HCOO)(5)(-)](n) and, compared with the starting material, shows antiferromagnetic behavior as the well-known inorganic Cu-O, Co-O square layers for creating inorganic conducting magnets. Long-range antiferromagnetic ordering was observed at 8.0 K.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38503]
专题	化学研究所_有机固体实验室
作者单位	1.Chinese Acad Sci, CMS, Educ Ctr Excellence Mol Sci, Organ Solid Lab,CAS Res, Beijing 100190, Peoples R China 2.Chinese Acad Sci, BNLMS, Inst Chem, Beijing 100190, Peoples R China 3.Peking Univ, Sch Phys, Inst Condensed Matter & Mat Phys, Beijing 100871, Peoples R China 4.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China 5.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100047, Peoples R China 6.Chinese Acad Sci, CMS, Beijing 100190, Peoples R China 7.Chinese Acad Sci, BNLMS, Inst Chem, Beijing 100190, Peoples R China 8.Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Bin,Zhang, Yan,Wang, Zheming,et al. BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet[J]. CHEMISTRYOPEN,2017,6(3):320-324.
APA	Zhang, Bin.,Zhang, Yan.,Wang, Zheming.,Gao, Zengqiang.,Yang, Deliang.,...&Zhu, Daoben.(2017).BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet.CHEMISTRYOPEN,6(3),320-324.
MLA	Zhang, Bin,et al."BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet".CHEMISTRYOPEN 6.3(2017):320-324.