From zinc-cyanide hybrid coordination polymers to hierarchical yolk-shell structures for high-performance and ultra-stable lithium-ion batteries
Fan, Haosen1,2,3; Yu, Hong2; Zhang, Yufei2; Guo, Jing1; Wang, Zhen1; Wang, Hao1; Hao, Xi1; Zhao, Ning1; Geng, Hongbo2; Dai, Zhengfei2
刊名NANO ENERGY
2017-03-01
卷号33页码:168-176
关键词Coordination Polymers Batteries Ultra-stable Yolk-shell Zno@c Nanocrystal
英文摘要Uniform zinc-cyanide hybrid coordination polymer microspheres were successfully synthesized by a coprecipitation method. Then hierarchical yolk-shell structured and carbon coated ZnO microspheres (YC-ZnO) composed of ZnO@C nanocrystals were prepared by consecutive post annealing processes of these microspheres in argon and air atmosphere. Such micro-nano porous structures have the advantages of large specific surface area, good charge transport kinetics, and large cavity to accommodate the volume change and maintain the mechanical integrity of the electrode material. When evaluated as anode materials of lithium ion batteries, these ZnO yolk-shell spheres exhibited excellent battery performance with a high rate capacity and ultra-stable cycling stability.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38207]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
3.Nanyang Technol Univ, Energy Res Inst NTU, Res Techno Plaza, Singapore 637553, Singapore
推荐引用方式
GB/T 7714
Fan, Haosen,Yu, Hong,Zhang, Yufei,et al. From zinc-cyanide hybrid coordination polymers to hierarchical yolk-shell structures for high-performance and ultra-stable lithium-ion batteries[J]. NANO ENERGY,2017,33:168-176.
APA Fan, Haosen.,Yu, Hong.,Zhang, Yufei.,Guo, Jing.,Wang, Zhen.,...&Xu, Jian.(2017).From zinc-cyanide hybrid coordination polymers to hierarchical yolk-shell structures for high-performance and ultra-stable lithium-ion batteries.NANO ENERGY,33,168-176.
MLA Fan, Haosen,et al."From zinc-cyanide hybrid coordination polymers to hierarchical yolk-shell structures for high-performance and ultra-stable lithium-ion batteries".NANO ENERGY 33(2017):168-176.
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