Nitrogen, phosphorus and sulfur co-doped ultrathin carbon nanosheets as a metal-free catalyst for selective oxidation of aromatic alkanes and the oxygen reduction reaction

CORC > 化学研究所 > 中国科学院化学研究所 > 分子纳米结构与纳米技术实验室

	Nitrogen, phosphorus and sulfur co-doped ultrathin carbon nanosheets as a metal-free catalyst for selective oxidation of aromatic alkanes and the oxygen reduction reaction
	Zhu, Ya-Nan 1,2; Cao, Chang-Yan 1,2; Jiang, Wen-Jie 1,2; Yang, Shu-Liang 1,2; Hu, Jin-Song 1; Song, Wei-Guo 1,2; Wan, Li -Jun 1
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2016-12-21
卷号	4 期号:47 页码:18470-18477
英文摘要	Carbon materials have attracted considerable interest as metal-free heterogeneous catalysts owing to their superior physicochemical properties, including low cost, stability, and easily tailorable structures as well as excellent catalytic activity. In this study, we have designed an efficient method to produce ultrathin carbon nanosheets (similar to 2.2 nm) with multi-heteroatom (nitrogen, phosphorus and sulfur) doping and a high surface area (up to 1198 m(2) g(-1)). This method employs poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) as the main carbon source and N,P,S-doping sources, while g-C3N4 nanosheets act as the morphology template, extra N doping source and porogen. The doped carbon nanosheets are an excellent metal-free carbocatalyst for selective oxidation of aromatic alkanes in aqueous solution and electrochemical catalyst for the oxygen reduction reaction in an alkaline medium.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/37992]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Ya-Nan,Cao, Chang-Yan,Jiang, Wen-Jie,et al. Nitrogen, phosphorus and sulfur co-doped ultrathin carbon nanosheets as a metal-free catalyst for selective oxidation of aromatic alkanes and the oxygen reduction reaction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(47):18470-18477.
APA	Zhu, Ya-Nan.,Cao, Chang-Yan.,Jiang, Wen-Jie.,Yang, Shu-Liang.,Hu, Jin-Song.,...&Wan, Li -Jun.(2016).Nitrogen, phosphorus and sulfur co-doped ultrathin carbon nanosheets as a metal-free catalyst for selective oxidation of aromatic alkanes and the oxygen reduction reaction.JOURNAL OF MATERIALS CHEMISTRY A,4(47),18470-18477.
MLA	Zhu, Ya-Nan,et al."Nitrogen, phosphorus and sulfur co-doped ultrathin carbon nanosheets as a metal-free catalyst for selective oxidation of aromatic alkanes and the oxygen reduction reaction".JOURNAL OF MATERIALS CHEMISTRY A 4.47(2016):18470-18477.