Engineering studies on the direct synthesis of methyl chlorosilane in fluidized bed reactor with multiple tubular and segmented heat transfer

doi:10.15199/62.2018.7.22

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 资源化学研究室

	Engineering studies on the direct synthesis of methyl chlorosilane in fluidized bed reactor with multiple tubular and segmented heat transfer
	Wang, Q (Wang Qiang)[ 1,2 ]; Zhang, ZW (Zhang Zhengwei)[ 1 ]; Wang, X (Wang Xu)[ 1 ]; Gao, L (Gao Lin)[ 1 ]
刊名	PRZEMYSL CHEMICZNY
	2018
卷号	97 期号:7 页码:1144-1150
ISSN号	0033-2496
DOI	10.15199/62.2018.7.22
英文摘要	The fluidized bed reactor with multiple tubular and segmented heat transfer was employed to study the effects of mass flow rate of MeCl and reaction pressure on the rate of MeCl conversion and the methyl chlorosilane yield at 300 degrees C. The rate of MeCl conversion and the yield of Me2SiCl2 were not always increased with increasing mass flow rate of MeCl at constant reaction pressure under particular operating conditions. At constant mass flow rate, the rate of MeCl conversion and the yield of Me2SiCl2 decreased first, and then increased with increasing reaction pressure. Therefore, for the fluidized bed reaction system, a synergism between the MeCl mass flow and reaction pressure in effecting the MeCl conversion rate and the yield of Me2SiCl2 was obsd. The reaction pressure for optimum yield of Me2SiCl2 was 0.30 MPa and MeCl mass flow rate was 4.5 kg/h.
WOS记录号	WOS:000443795000025
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5573]
专题	新疆理化技术研究所_资源化学研究室
通讯作者	Wang, Q (Wang Qiang)[ 1,2 ]
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Q ,Zhang, ZW ,Wang, X ,et al. Engineering studies on the direct synthesis of methyl chlorosilane in fluidized bed reactor with multiple tubular and segmented heat transfer[J]. PRZEMYSL CHEMICZNY,2018,97(7):1144-1150.
APA	Wang, Q ,Zhang, ZW ,Wang, X ,&Gao, L .(2018).Engineering studies on the direct synthesis of methyl chlorosilane in fluidized bed reactor with multiple tubular and segmented heat transfer.PRZEMYSL CHEMICZNY,97(7),1144-1150.
MLA	Wang, Q ,et al."Engineering studies on the direct synthesis of methyl chlorosilane in fluidized bed reactor with multiple tubular and segmented heat transfer".PRZEMYSL CHEMICZNY 97.7(2018):1144-1150.