Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes

doi:10.1039/c8cc00345a

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 省部共建新疆特有药用资源利用重点实验室

	Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes
	Feng, J (Feng, Jie); Ma, PJ (Ma, Peng-Ju); Zeng, YM (Zeng, Yong-Ming); Xu, YJ (Xu, Yan-Jun); Lu, CD (Lu, Chong-Dao)
刊名	CHEMICAL COMMUNICATIONS
	2018
卷号	54 期号:23 页码:2882-2885
ISSN号	1359-7345
DOI	10.1039/c8cc00345a
英文摘要	A dimethyl phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes was developed. Nitrosoarenes were successfully used as electrophiles to trap aza-enolate intermediates that were generated from nucleophilic addition of deprotonated phosphite to alpha-keto N-tert-butanesulfinyl imidates and following phospha-Brook rearrangement, allowing efficient construction of ketonitrones with excellent (Z)-geometries.
WOS记录号	WOS:000428844500013
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5271]
专题	新疆理化技术研究所_省部共建新疆特有药用资源利用重点实验室
通讯作者	Lu, CD (Lu, Chong-Dao)
作者单位	1.Changji Univ, Dept Chem & Appl Chem, Changji 831100, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Feng, J ,Ma, PJ ,Zeng, YM ,et al. Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes[J]. CHEMICAL COMMUNICATIONS,2018,54(23):2882-2885.
APA	Feng, J ,Ma, PJ ,Zeng, YM ,Xu, YJ ,&Lu, CD .(2018).Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes.CHEMICAL COMMUNICATIONS,54(23),2882-2885.
MLA	Feng, J ,et al."Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes".CHEMICAL COMMUNICATIONS 54.23(2018):2882-2885.