Structural Insights into Borates with an Anion-Templated Open-Framework Configuration: Asymmetric K2 BaB16 O26 versus Centrosymmetric K3 CsB20 O32 and Na2 M2 NB18 O30 (M=Rb, Cs; N=Ba, Pb). | |
Mutailipu, Miriding; Zhang, Min; Su, Xin; Yang, Zhihua; Chen, Yanna; Pan, Shilie | |
刊名 | Chemistry - A European Journal |
2017 | |
卷号 | 23期号:56页码:13910–13918 |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201702891 |
英文摘要 | Five new mixed-metal borate crystals, namely, K2 BaB16 O26 , K3 CsB20 O32 , Na2 Cs2 BaB18 O30 , Na2 Rb2 PbB18 O30 , and Na2 Cs2 PbB18 O30 , have been synthesized by the high-temperature solution method. These structures were characterized by single-crystal X-ray diffraction and their B-O configurations are shown to feature complicated three-dimensional (3D) open-framework structures incorporating different types of channels. For all five compounds, the frameworks can be reduced to four-connected (4-c) uninodal nets with sra-, dia- and nbo-type topologies by assigning the [B5 O10 ]5- and [B3 O7 ]5- clusters as basic nodes. First-principles calculations have shown that the multiple cations in mixed-metal borates influence the ground-state electronic structures and associated optical absorptions. In addition, the crystal structures, thermal stabilities, and IR spectra of the title compounds have also been performed. |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/4925] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Zhang, Min; Yang, Zhihua; Pan, Shilie |
作者单位 | 1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condense, Yining 835000, Xinjiang, Peoples R China |
推荐引用方式 GB/T 7714 | Mutailipu, Miriding,Zhang, Min,Su, Xin,et al. Structural Insights into Borates with an Anion-Templated Open-Framework Configuration: Asymmetric K2 BaB16 O26 versus Centrosymmetric K3 CsB20 O32 and Na2 M2 NB18 O30 (M=Rb, Cs; N=Ba, Pb).[J]. Chemistry - A European Journal,2017,23(56):13910–13918. |
APA | Mutailipu, Miriding,Zhang, Min,Su, Xin,Yang, Zhihua,Chen, Yanna,&Pan, Shilie.(2017).Structural Insights into Borates with an Anion-Templated Open-Framework Configuration: Asymmetric K2 BaB16 O26 versus Centrosymmetric K3 CsB20 O32 and Na2 M2 NB18 O30 (M=Rb, Cs; N=Ba, Pb)..Chemistry - A European Journal,23(56),13910–13918. |
MLA | Mutailipu, Miriding,et al."Structural Insights into Borates with an Anion-Templated Open-Framework Configuration: Asymmetric K2 BaB16 O26 versus Centrosymmetric K3 CsB20 O32 and Na2 M2 NB18 O30 (M=Rb, Cs; N=Ba, Pb).".Chemistry - A European Journal 23.56(2017):13910–13918. |
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