CHIRAL LIGANDS DERIVED FROM ABRINE .1. SYNTHESIS OF SEC-BETA-AMINO AND TERT-BETA-AMINO ALCOHOLS AND CATALYSIS FOR ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TOWARD AROMATIC-ALDEHYDES

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	CHIRAL LIGANDS DERIVED FROM ABRINE .1. SYNTHESIS OF SEC-BETA-AMINO AND TERT-BETA-AMINO ALCOHOLS AND CATALYSIS FOR ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TOWARD AROMATIC-ALDEHYDES
	DAI, WM; ZHU, HJ; HAO, XJ
刊名	TETRAHEDRON-ASYMMETRY
	1995-08-01
卷号	6 期号:8 页码:1857-1860
关键词	Asymmetric Induction Reagents Dialkylzincs
ISSN号	0957-4166
英文摘要	A number of indole-containing chiral beta-amino alcohols 3a-d and 9a-e have been synthesized from the alkaloid, Abrine (1) readily available from seeds of Abrus precatorius collected in Yunnan Province of China Catalysis of the synthesized chiral ligands for the addition of diethylzinc toward benzaldehyde was examined. A significant role of the substituent(s) in the catalyst on the degree of asymmetric induction was uncovered. Enantiomeric excess of the product up to 94.2% was recorded.
学科主题	Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
语种	英语
WOS记录号	WOS:A1995RU27900009
公开日期	2012-03-21
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn:8080/handle/151853/4356]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	CHINESE ACAD SCI,KUNMING INST BOT,KUNMING 650204,PEOPLES R CHINA
推荐引用方式 GB/T 7714	DAI, WM,ZHU, HJ,HAO, XJ. CHIRAL LIGANDS DERIVED FROM ABRINE .1. SYNTHESIS OF SEC-BETA-AMINO AND TERT-BETA-AMINO ALCOHOLS AND CATALYSIS FOR ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TOWARD AROMATIC-ALDEHYDES[J]. TETRAHEDRON-ASYMMETRY,1995,6(8):1857-1860.
APA	DAI, WM,ZHU, HJ,&HAO, XJ.(1995).CHIRAL LIGANDS DERIVED FROM ABRINE .1. SYNTHESIS OF SEC-BETA-AMINO AND TERT-BETA-AMINO ALCOHOLS AND CATALYSIS FOR ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TOWARD AROMATIC-ALDEHYDES.TETRAHEDRON-ASYMMETRY,6(8),1857-1860.
MLA	DAI, WM,et al."CHIRAL LIGANDS DERIVED FROM ABRINE .1. SYNTHESIS OF SEC-BETA-AMINO AND TERT-BETA-AMINO ALCOHOLS AND CATALYSIS FOR ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TOWARD AROMATIC-ALDEHYDES".TETRAHEDRON-ASYMMETRY 6.8(1995):1857-1860.